Synthesis of 1,3,4,6-Tetra-O-acetyl-l-gulose

Rui Che; Xingui Liu; Wei Lu

doi:10.1002/cjoc.201600658

Synthesis of 1,3,4,6-Tetra-O-acetyl-l-gulose

Rui Che, Xingui Liu, Wei Lu

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Comment/debate

4 Scopus citations

Abstract

A novel, practical and concise synthesis of 1,3,4,6-tetra-O-acetyl-l-gulose is described, using d-glucuronolactone as the starting material and other inexpensive and readily available agents (22% overall yield in 9 steps). With this method, the synthesis of l-gulose and the tumor-targeting disaccharide of BLMs can be more efficient and convenient.

Original language	English
Pages (from-to)	237-241
Number of pages	5
Journal	Chinese Journal of Chemistry
Volume	35
Issue number	2
DOIs	https://doi.org/10.1002/cjoc.201600658
State	Published - Feb 2017

Keywords

bleomycins
d-glucuronolactone
l-gulose

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10.1002/cjoc.201600658

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title = "Synthesis of 1,3,4,6-Tetra-O-acetyl-l-gulose",

abstract = "A novel, practical and concise synthesis of 1,3,4,6-tetra-O-acetyl-l-gulose is described, using d-glucuronolactone as the starting material and other inexpensive and readily available agents (22\% overall yield in 9 steps). With this method, the synthesis of l-gulose and the tumor-targeting disaccharide of BLMs can be more efficient and convenient.",

keywords = "bleomycins, d-glucuronolactone, l-gulose",

author = "Rui Che and Xingui Liu and Wei Lu",

note = "Publisher Copyright: {\textcopyright} 2017 SIOC, CAS, Shanghai \& WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = feb,

doi = "10.1002/cjoc.201600658",

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volume = "35",

pages = "237--241",

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TY - JOUR

T1 - Synthesis of 1,3,4,6-Tetra-O-acetyl-l-gulose

AU - Che, Rui

AU - Liu, Xingui

AU - Lu, Wei

PY - 2017/2

Y1 - 2017/2

N2 - A novel, practical and concise synthesis of 1,3,4,6-tetra-O-acetyl-l-gulose is described, using d-glucuronolactone as the starting material and other inexpensive and readily available agents (22% overall yield in 9 steps). With this method, the synthesis of l-gulose and the tumor-targeting disaccharide of BLMs can be more efficient and convenient.

AB - A novel, practical and concise synthesis of 1,3,4,6-tetra-O-acetyl-l-gulose is described, using d-glucuronolactone as the starting material and other inexpensive and readily available agents (22% overall yield in 9 steps). With this method, the synthesis of l-gulose and the tumor-targeting disaccharide of BLMs can be more efficient and convenient.

KW - bleomycins

KW - d-glucuronolactone

KW - l-gulose

UR - https://www.scopus.com/pages/publications/85007168379

U2 - 10.1002/cjoc.201600658

DO - 10.1002/cjoc.201600658

M3 - 评论/辩论

AN - SCOPUS:85007168379

SN - 1001-604X

VL - 35

SP - 237

EP - 241

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 2

ER -

Synthesis of 1,3,4,6-Tetra-O-acetyl-l-gulose

Abstract

Keywords

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