Synthesis of γ-Sulfur-Substituted Ketones via Rh(II)/Sc(III) a Cocatalyzed Three-Component Reaction of Diazo Compounds with Thiophenols and Enones

Guolan Xiao; Chaoqun Ma; Xiang Wu; Dong Xing; Wenhao Hu

doi:10.1021/acs.joc.7b03074

Synthesis of γ-Sulfur-Substituted Ketones via Rh(II)/Sc(III) a Cocatalyzed Three-Component Reaction of Diazo Compounds with Thiophenols and Enones

Guolan Xiao
, Chaoqun Ma
, Xiang Wu
, Dong Xing^*
, Wenhao Hu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
Sun Yat-Sen University

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A facile method for the synthesis of γ-sulfur-substituted ketones is developed via a Rh(II)/Sc(III) cocatalyzed three-component reaction of diazo compounds with thiophenols and enones. With this method, different γ-sulfur-substituted ketones were obtained in moderate to high yields with good diastereoselectivities.

Original language	English
Pages (from-to)	4786-4791
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	83
Issue number	8
DOIs	https://doi.org/10.1021/acs.joc.7b03074
State	Published - 20 Apr 2018

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title = "Synthesis of γ-Sulfur-Substituted Ketones via Rh(II)/Sc(III) a Cocatalyzed Three-Component Reaction of Diazo Compounds with Thiophenols and Enones",

abstract = "A facile method for the synthesis of γ-sulfur-substituted ketones is developed via a Rh(II)/Sc(III) cocatalyzed three-component reaction of diazo compounds with thiophenols and enones. With this method, different γ-sulfur-substituted ketones were obtained in moderate to high yields with good diastereoselectivities.",

author = "Guolan Xiao and Chaoqun Ma and Xiang Wu and Dong Xing and Wenhao Hu",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

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doi = "10.1021/acs.joc.7b03074",

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T1 - Synthesis of γ-Sulfur-Substituted Ketones via Rh(II)/Sc(III) a Cocatalyzed Three-Component Reaction of Diazo Compounds with Thiophenols and Enones

AU - Xiao, Guolan

AU - Ma, Chaoqun

AU - Wu, Xiang

AU - Xing, Dong

AU - Hu, Wenhao

PY - 2018/4/20

Y1 - 2018/4/20

N2 - A facile method for the synthesis of γ-sulfur-substituted ketones is developed via a Rh(II)/Sc(III) cocatalyzed three-component reaction of diazo compounds with thiophenols and enones. With this method, different γ-sulfur-substituted ketones were obtained in moderate to high yields with good diastereoselectivities.

AB - A facile method for the synthesis of γ-sulfur-substituted ketones is developed via a Rh(II)/Sc(III) cocatalyzed three-component reaction of diazo compounds with thiophenols and enones. With this method, different γ-sulfur-substituted ketones were obtained in moderate to high yields with good diastereoselectivities.

UR - https://www.scopus.com/pages/publications/85045725759

U2 - 10.1021/acs.joc.7b03074

DO - 10.1021/acs.joc.7b03074

M3 - 文章

C2 - 29565132

AN - SCOPUS:85045725759

SN - 0022-3263

VL - 83

SP - 4786

EP - 4791

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 8

ER -

Synthesis of γ-Sulfur-Substituted Ketones via Rh(II)/Sc(III) a Cocatalyzed Three-Component Reaction of Diazo Compounds with Thiophenols and Enones

Abstract

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