Synthesis, characterization of Zn-containing tungstomolybdosilic polyoxometalates and their catalytic performance in reaction of 2-propanol

Chun Yan Hua; Juan Li; Li Yi Dai; Yong Kui Shan

Synthesis, characterization of Zn-containing tungstomolybdosilic polyoxometalates and their catalytic performance in reaction of 2-propanol

Chun Yan Hua^*
, Juan Li
, Li Yi Dai
, Yong Kui Shan

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Zn-containing derivatives of H₄SiMo_12-nW _nO₄₀ (n=2, 4, 6, 8, 10) were prepared under different pH according to the variation of n and characterized by elemental analysis, IR spectra, X-ray diffraction and XPS. The acid kind and intensity of the polyoxometalates were investigated by Py-IR and NH₃-TPD, respectively. The polyoxometalates were used as heterogeneous catalysts in tested gaseous reaction of decomposition of isopropanol. The relationship between catalytic activity of the polyoxometalates and their component was discussed.

Original language	English
Pages (from-to)	2082-2088
Number of pages	7
Journal	Acta Chimica Sinica
Volume	63
Issue number	22
State	Published - 2005

Keywords

Catalysis
Isopropanol
Keggin structure
Polyoxometalate
Zinc

Cite this

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title = "Synthesis, characterization of Zn-containing tungstomolybdosilic polyoxometalates and their catalytic performance in reaction of 2-propanol",

abstract = "Zn-containing derivatives of H4SiMo12-nW nO40 (n=2, 4, 6, 8, 10) were prepared under different pH according to the variation of n and characterized by elemental analysis, IR spectra, X-ray diffraction and XPS. The acid kind and intensity of the polyoxometalates were investigated by Py-IR and NH3-TPD, respectively. The polyoxometalates were used as heterogeneous catalysts in tested gaseous reaction of decomposition of isopropanol. The relationship between catalytic activity of the polyoxometalates and their component was discussed.",

keywords = "Catalysis, Isopropanol, Keggin structure, Polyoxometalate, Zinc",

author = "Hua, \{Chun Yan\} and Juan Li and Dai, \{Li Yi\} and Shan, \{Yong Kui\}",

year = "2005",

language = "英语",

volume = "63",

pages = "2082--2088",

journal = "Acta Chimica Sinica",

issn = "0567-7351",

publisher = "Editorial Office of Acta Chimica Sinica",

number = "22",

}

TY - JOUR

T1 - Synthesis, characterization of Zn-containing tungstomolybdosilic polyoxometalates and their catalytic performance in reaction of 2-propanol

AU - Hua, Chun Yan

AU - Li, Juan

AU - Dai, Li Yi

AU - Shan, Yong Kui

PY - 2005

Y1 - 2005

N2 - Zn-containing derivatives of H4SiMo12-nW nO40 (n=2, 4, 6, 8, 10) were prepared under different pH according to the variation of n and characterized by elemental analysis, IR spectra, X-ray diffraction and XPS. The acid kind and intensity of the polyoxometalates were investigated by Py-IR and NH3-TPD, respectively. The polyoxometalates were used as heterogeneous catalysts in tested gaseous reaction of decomposition of isopropanol. The relationship between catalytic activity of the polyoxometalates and their component was discussed.

AB - Zn-containing derivatives of H4SiMo12-nW nO40 (n=2, 4, 6, 8, 10) were prepared under different pH according to the variation of n and characterized by elemental analysis, IR spectra, X-ray diffraction and XPS. The acid kind and intensity of the polyoxometalates were investigated by Py-IR and NH3-TPD, respectively. The polyoxometalates were used as heterogeneous catalysts in tested gaseous reaction of decomposition of isopropanol. The relationship between catalytic activity of the polyoxometalates and their component was discussed.

KW - Catalysis

KW - Isopropanol

KW - Keggin structure

KW - Polyoxometalate

KW - Zinc

UR - https://www.scopus.com/pages/publications/33750523864

M3 - 文章

AN - SCOPUS:33750523864

SN - 0567-7351

VL - 63

SP - 2082

EP - 2088

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

IS - 22

ER -

Synthesis, characterization of Zn-containing tungstomolybdosilic polyoxometalates and their catalytic performance in reaction of 2-propanol

Abstract

Keywords

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