Synthesis, characterization and sulfide oxidation activity of vanadyl Schiff base complexes anchored on MCM-41

Guohua Gao; Jinbao Gao; Liang Lu; Wenjuan Zhou; Mingyuan He

doi:10.1007/s10934-007-9112-8

Synthesis, characterization and sulfide oxidation activity of vanadyl Schiff base complexes anchored on MCM-41

Guohua Gao^*
, Jinbao Gao
, Liang Lu
, Wenjuan Zhou
, Mingyuan He

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Vanadyl Schiff base complexes covalently attached on the surface of MCM-41 have been synthesized by anchoring Schiff base and subsequent reaction with VO(acac)₂. XRD, nitrogen adsorption and desorption, UV-visible spectroscopy and FT-IR show that vanadyl Schiff base complexes were successfully anchored on the surface of MCM-41 and the mesopore ordering decreased after the anchoring. The so-prepared heterogeneous catalysts have showed high activity for sulfide oxidation.

Original language	English
Pages (from-to)	127-132
Number of pages	6
Journal	Journal of Porous Materials
Volume	15
Issue number	2
DOIs	https://doi.org/10.1007/s10934-007-9112-8
State	Published - Apr 2008

Keywords

Heterogeneous catalysis
Mesoporous
Sulfide oxidation
Vanadyl Schiff base complexes

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title = "Synthesis, characterization and sulfide oxidation activity of vanadyl Schiff base complexes anchored on MCM-41",

abstract = "Vanadyl Schiff base complexes covalently attached on the surface of MCM-41 have been synthesized by anchoring Schiff base and subsequent reaction with VO(acac)2. XRD, nitrogen adsorption and desorption, UV-visible spectroscopy and FT-IR show that vanadyl Schiff base complexes were successfully anchored on the surface of MCM-41 and the mesopore ordering decreased after the anchoring. The so-prepared heterogeneous catalysts have showed high activity for sulfide oxidation.",

keywords = "Heterogeneous catalysis, Mesoporous, Sulfide oxidation, Vanadyl Schiff base complexes",

author = "Guohua Gao and Jinbao Gao and Liang Lu and Wenjuan Zhou and Mingyuan He",

year = "2008",

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doi = "10.1007/s10934-007-9112-8",

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T1 - Synthesis, characterization and sulfide oxidation activity of vanadyl Schiff base complexes anchored on MCM-41

AU - Gao, Guohua

AU - Gao, Jinbao

AU - Lu, Liang

AU - Zhou, Wenjuan

AU - He, Mingyuan

PY - 2008/4

Y1 - 2008/4

N2 - Vanadyl Schiff base complexes covalently attached on the surface of MCM-41 have been synthesized by anchoring Schiff base and subsequent reaction with VO(acac)2. XRD, nitrogen adsorption and desorption, UV-visible spectroscopy and FT-IR show that vanadyl Schiff base complexes were successfully anchored on the surface of MCM-41 and the mesopore ordering decreased after the anchoring. The so-prepared heterogeneous catalysts have showed high activity for sulfide oxidation.

AB - Vanadyl Schiff base complexes covalently attached on the surface of MCM-41 have been synthesized by anchoring Schiff base and subsequent reaction with VO(acac)2. XRD, nitrogen adsorption and desorption, UV-visible spectroscopy and FT-IR show that vanadyl Schiff base complexes were successfully anchored on the surface of MCM-41 and the mesopore ordering decreased after the anchoring. The so-prepared heterogeneous catalysts have showed high activity for sulfide oxidation.

KW - Heterogeneous catalysis

KW - Mesoporous

KW - Sulfide oxidation

KW - Vanadyl Schiff base complexes

UR - https://www.scopus.com/pages/publications/40149106818

U2 - 10.1007/s10934-007-9112-8

DO - 10.1007/s10934-007-9112-8

M3 - 文章

AN - SCOPUS:40149106818

SN - 1380-2224

VL - 15

SP - 127

EP - 132

JO - Journal of Porous Materials

JF - Journal of Porous Materials

IS - 2

ER -

Synthesis, characterization and sulfide oxidation activity of vanadyl Schiff base complexes anchored on MCM-41

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Keywords

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