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Synthesis and structure revision of nakiterpiosin

  • Shuanhu Gao*
  • , Qiaoling Wang
  • , Chuo Chen
  • *Corresponding author for this work
  • University of Texas Southwestern Medical Center

Research output: Contribution to journalArticlepeer-review

Abstract

This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.

Original languageEnglish
Pages (from-to)1410-1412
Number of pages3
JournalJournal of the American Chemical Society
Volume131
Issue number4
DOIs
StatePublished - 4 Feb 2009
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 14 - Life Below Water
    SDG 14 Life Below Water

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