Synthesis and structure revision of nakiterpiosin

Shuanhu Gao; Qiaoling Wang; Chuo Chen

doi:10.1021/ja808110d

Synthesis and structure revision of nakiterpiosin

Shuanhu Gao^*
, Qiaoling Wang
, Chuo Chen

^*Corresponding author for this work

University of Texas Southwestern Medical Center

Research output: Contribution to journal › Article › peer-review

125 Scopus citations

Abstract

This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.

Original language	English
Pages (from-to)	1410-1412
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	131
Issue number	4
DOIs	https://doi.org/10.1021/ja808110d
State	Published - 4 Feb 2009
Externally published	Yes

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10.1021/ja808110d

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title = "Synthesis and structure revision of nakiterpiosin",

abstract = "This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.",

author = "Shuanhu Gao and Qiaoling Wang and Chuo Chen",

year = "2009",

month = feb,

day = "4",

doi = "10.1021/ja808110d",

language = "英语",

volume = "131",

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journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Synthesis and structure revision of nakiterpiosin

AU - Gao, Shuanhu

AU - Wang, Qiaoling

AU - Chen, Chuo

PY - 2009/2/4

Y1 - 2009/2/4

N2 - This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.

AB - This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.

UR - https://www.scopus.com/pages/publications/63149143373

U2 - 10.1021/ja808110d

DO - 10.1021/ja808110d

M3 - 文章

C2 - 18998640

AN - SCOPUS:63149143373

SN - 0002-7863

VL - 131

SP - 1410

EP - 1412

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 4

ER -

Synthesis and structure revision of nakiterpiosin

Abstract

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