Synthesis and structure of three dichromium hexacarbonyl complexes with (CPPh2)2, (CHPPh2)2, and carbazole bridges

Xiaohui Tian; Haitao Sun; Yizhong Yuan; Jiaping Lin; Lixian Liang; Yanchao Che

doi:10.1016/j.tet.2010.09.058

Synthesis and structure of three dichromium hexacarbonyl complexes with (CPPh₂)₂, (CHPPh₂)₂, and carbazole bridges

Xiaohui Tian^*
, Haitao Sun
, Yizhong Yuan
, Jiaping Lin
, Lixian Liang
, Yanchao Che

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Three dichromium hexacarbonyl complexes containing (CPPh₂) ₂, (CHPPh₂)₂, and carbazole as a conjugated bridging ligand are synthesized and exhibit a variety of electronic interactions between the metal centers, which can be modified by altering either the conjugated bridging nature or the ligand bound to the metals to induce peculiar asymmetry.

Original language	English
Pages (from-to)	9456-9460
Number of pages	5
Journal	Tetrahedron
Volume	66
Issue number	48
DOIs	https://doi.org/10.1016/j.tet.2010.09.058
State	Published - 27 Nov 2010
Externally published	Yes

Keywords

Conjugated bridging ligand
DFT
Dichromium hexacarbonyl complex
Electronic interaction
MLCT

Access to Document

10.1016/j.tet.2010.09.058

Cite this

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title = "Synthesis and structure of three dichromium hexacarbonyl complexes with (CPPh2)2, (CHPPh2)2, and carbazole bridges",

abstract = "Three dichromium hexacarbonyl complexes containing (CPPh2) 2, (CHPPh2)2, and carbazole as a conjugated bridging ligand are synthesized and exhibit a variety of electronic interactions between the metal centers, which can be modified by altering either the conjugated bridging nature or the ligand bound to the metals to induce peculiar asymmetry.",

keywords = "Conjugated bridging ligand, DFT, Dichromium hexacarbonyl complex, Electronic interaction, MLCT",

author = "Xiaohui Tian and Haitao Sun and Yizhong Yuan and Jiaping Lin and Lixian Liang and Yanchao Che",

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T1 - Synthesis and structure of three dichromium hexacarbonyl complexes with (CPPh2)2, (CHPPh2)2, and carbazole bridges

AU - Tian, Xiaohui

AU - Sun, Haitao

AU - Yuan, Yizhong

AU - Lin, Jiaping

AU - Liang, Lixian

AU - Che, Yanchao

PY - 2010/11/27

Y1 - 2010/11/27

N2 - Three dichromium hexacarbonyl complexes containing (CPPh2) 2, (CHPPh2)2, and carbazole as a conjugated bridging ligand are synthesized and exhibit a variety of electronic interactions between the metal centers, which can be modified by altering either the conjugated bridging nature or the ligand bound to the metals to induce peculiar asymmetry.

AB - Three dichromium hexacarbonyl complexes containing (CPPh2) 2, (CHPPh2)2, and carbazole as a conjugated bridging ligand are synthesized and exhibit a variety of electronic interactions between the metal centers, which can be modified by altering either the conjugated bridging nature or the ligand bound to the metals to induce peculiar asymmetry.

KW - Conjugated bridging ligand

KW - DFT

KW - Dichromium hexacarbonyl complex

KW - Electronic interaction

KW - MLCT

UR - https://www.scopus.com/pages/publications/78049463053

U2 - 10.1016/j.tet.2010.09.058

DO - 10.1016/j.tet.2010.09.058

M3 - 文章

AN - SCOPUS:78049463053

SN - 0040-4020

VL - 66

SP - 9456

EP - 9460

JO - Tetrahedron

JF - Tetrahedron

IS - 48