Synthesis and structure of the first protonated zincoborophosphate: (H 3O)Zn(H2O)2BP2O8· H2O

Heng Zhen Shi; Yong Kui Shan; Ming Yuan He; Yu Yan Liu; Lin Hong Weng

doi:10.1002/cjoc.20030210913

Synthesis and structure of the first protonated zincoborophosphate: (H ₃O)Zn(H₂O)₂BP₂O₈· H₂O

Heng Zhen Shi^*
, Yong Kui Shan
, Ming Yuan He
, Yu Yan Liu
, Lin Hong Weng

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The solid acid of the first protonated zincoborophosphate, (H₃O) Zn (H₂O)₂BP₂O₈ · H ₂O (1), was soventothermally synthesized by the reaction of Zn (NO₃)₂ · 6H₂O and H₃BO ₃ with H₃PO₄ in a mixed solvent, and structurally characterized by single-crystal X-ray diffraction analysis. It crystallizes in the hexagonal P6₁22, a = 0.9604(4) nm, c = 1.5297(6) nm, V = 1.2218(8) nm³, D_c = 2.921 g/cm³, Z = 6, F (000) = 1080, μ = 3.495 mm^-1. The structure features that the tetrahedra-tetrahedra helices interconnected by octahedra and strong hydrogen bond interactions form a three-dimensional framework. The protonated water molecules are located at unique positions. Other characterizations by IR and thermal analysis are also described.

Original language	English
Pages (from-to)	1170-1173
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	21
Issue number	9
DOIs	https://doi.org/10.1002/cjoc.20030210913
State	Published - Sep 2003

Keywords

Helical ribbon
Protonation
Soventothermal synthesis
Structure
Zincoborophosphate

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title = "Synthesis and structure of the first protonated zincoborophosphate: (H 3O)Zn(H2O)2BP2O8· H2O",

abstract = "The solid acid of the first protonated zincoborophosphate, (H3O) Zn (H2O)2BP2O8 · H 2O (1), was soventothermally synthesized by the reaction of Zn (NO3)2 · 6H2O and H3BO 3 with H3PO4 in a mixed solvent, and structurally characterized by single-crystal X-ray diffraction analysis. It crystallizes in the hexagonal P6122, a = 0.9604(4) nm, c = 1.5297(6) nm, V = 1.2218(8) nm3, Dc = 2.921 g/cm3, Z = 6, F (000) = 1080, μ = 3.495 mm-1. The structure features that the tetrahedra-tetrahedra helices interconnected by octahedra and strong hydrogen bond interactions form a three-dimensional framework. The protonated water molecules are located at unique positions. Other characterizations by IR and thermal analysis are also described.",

keywords = "Helical ribbon, Protonation, Soventothermal synthesis, Structure, Zincoborophosphate",

author = "Shi, \{Heng Zhen\} and Shan, \{Yong Kui\} and He, \{Ming Yuan\} and Liu, \{Yu Yan\} and Weng, \{Lin Hong\}",

year = "2003",

month = sep,

doi = "10.1002/cjoc.20030210913",

language = "英语",

volume = "21",

pages = "1170--1173",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley and Sons Inc",

number = "9",

}

TY - JOUR

T1 - Synthesis and structure of the first protonated zincoborophosphate

T2 - (H 3O)Zn(H2O)2BP2O8· H2O

AU - Shi, Heng Zhen

AU - Shan, Yong Kui

AU - He, Ming Yuan

AU - Liu, Yu Yan

AU - Weng, Lin Hong

PY - 2003/9

Y1 - 2003/9

N2 - The solid acid of the first protonated zincoborophosphate, (H3O) Zn (H2O)2BP2O8 · H 2O (1), was soventothermally synthesized by the reaction of Zn (NO3)2 · 6H2O and H3BO 3 with H3PO4 in a mixed solvent, and structurally characterized by single-crystal X-ray diffraction analysis. It crystallizes in the hexagonal P6122, a = 0.9604(4) nm, c = 1.5297(6) nm, V = 1.2218(8) nm3, Dc = 2.921 g/cm3, Z = 6, F (000) = 1080, μ = 3.495 mm-1. The structure features that the tetrahedra-tetrahedra helices interconnected by octahedra and strong hydrogen bond interactions form a three-dimensional framework. The protonated water molecules are located at unique positions. Other characterizations by IR and thermal analysis are also described.

AB - The solid acid of the first protonated zincoborophosphate, (H3O) Zn (H2O)2BP2O8 · H 2O (1), was soventothermally synthesized by the reaction of Zn (NO3)2 · 6H2O and H3BO 3 with H3PO4 in a mixed solvent, and structurally characterized by single-crystal X-ray diffraction analysis. It crystallizes in the hexagonal P6122, a = 0.9604(4) nm, c = 1.5297(6) nm, V = 1.2218(8) nm3, Dc = 2.921 g/cm3, Z = 6, F (000) = 1080, μ = 3.495 mm-1. The structure features that the tetrahedra-tetrahedra helices interconnected by octahedra and strong hydrogen bond interactions form a three-dimensional framework. The protonated water molecules are located at unique positions. Other characterizations by IR and thermal analysis are also described.

KW - Helical ribbon

KW - Protonation

KW - Soventothermal synthesis

KW - Structure

KW - Zincoborophosphate

UR - https://www.scopus.com/pages/publications/33750081710

U2 - 10.1002/cjoc.20030210913

DO - 10.1002/cjoc.20030210913

M3 - 文章

AN - SCOPUS:33750081710

SN - 1001-604X

VL - 21

SP - 1170

EP - 1173

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 9

ER -

Synthesis and structure of the first protonated zincoborophosphate: (H ₃O)Zn(H₂O)₂BP₂O₈· H₂O

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Keywords

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