Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H3cth] [Fe(CN)6] • 3H2O

En Qing Gao; Jin Kui Tang; Xue Bing Leng; Dai Zheng Liao; Zong Hui Jiang; Shi Ping Yan

Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H₃cth] [Fe(CN)₆] • 3H₂O

En Qing Gao
, Jin Kui Tang
, Xue Bing Leng
, Dai Zheng Liao^*
, Zong Hui Jiang
, Shi Ping Yan

^*Corresponding author for this work

Nankai University
CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A hydrogen-bonded supramolecular compound, [H₃cth][Fe(CN)₆] • 3H₂O, was synthesized from meso-5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane(cth) and K₃ [Fe(CN)₆]. The compound crystallizes in triclinic space group P1, with a=0. 930 97(9) nm, b=1.051 60(11) nm, c=1. 638 47(17) nm, α=101. 077(2)°, β=90. 860(2)°, γ=111. 671(2)°, V=1. 456 4(3) nm³, Z = 2, R=0. 041 5. The structure consists of neutral two-dimensional sheets assembled via hydrogen bonds between the partially protonated macrocyclic tetraamine and the hexacyanoferrate(double-struck I sign) ion, while the hydrogen bonds involving water molecules interlink the sheets to form a unique three-dimensional supramolecular architecture.

Original language	English
Pages (from-to)	666
Number of pages	1
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	21
Issue number	5
State	Published - 10 May 2000
Externally published	Yes

Keywords

Crystal structure
Hydrogen bond
Macrocyclic compound
Supramolecule

Cite this

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title = "Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H3cth] [Fe(CN)6] • 3H2O",

abstract = "A hydrogen-bonded supramolecular compound, [H3cth][Fe(CN)6] • 3H2O, was synthesized from meso-5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane(cth) and K3 [Fe(CN)6]. The compound crystallizes in triclinic space group P1, with a=0. 930 97(9) nm, b=1.051 60(11) nm, c=1. 638 47(17) nm, α=101. 077(2)°, β=90. 860(2)°, γ=111. 671(2)°, V=1. 456 4(3) nm3, Z = 2, R=0. 041 5. The structure consists of neutral two-dimensional sheets assembled via hydrogen bonds between the partially protonated macrocyclic tetraamine and the hexacyanoferrate(double-struck I sign) ion, while the hydrogen bonds involving water molecules interlink the sheets to form a unique three-dimensional supramolecular architecture.",

keywords = "Crystal structure, Hydrogen bond, Macrocyclic compound, Supramolecule",

author = "Gao, \{En Qing\} and Tang, \{Jin Kui\} and Leng, \{Xue Bing\} and Liao, \{Dai Zheng\} and Jiang, \{Zong Hui\} and Yan, \{Shi Ping\}",

year = "2000",

month = may,

day = "10",

language = "英语",

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pages = "666",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

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T1 - Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H3cth] [Fe(CN)6] • 3H2O

AU - Gao, En Qing

AU - Tang, Jin Kui

AU - Leng, Xue Bing

AU - Liao, Dai Zheng

AU - Jiang, Zong Hui

AU - Yan, Shi Ping

PY - 2000/5/10

Y1 - 2000/5/10

N2 - A hydrogen-bonded supramolecular compound, [H3cth][Fe(CN)6] • 3H2O, was synthesized from meso-5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane(cth) and K3 [Fe(CN)6]. The compound crystallizes in triclinic space group P1, with a=0. 930 97(9) nm, b=1.051 60(11) nm, c=1. 638 47(17) nm, α=101. 077(2)°, β=90. 860(2)°, γ=111. 671(2)°, V=1. 456 4(3) nm3, Z = 2, R=0. 041 5. The structure consists of neutral two-dimensional sheets assembled via hydrogen bonds between the partially protonated macrocyclic tetraamine and the hexacyanoferrate(double-struck I sign) ion, while the hydrogen bonds involving water molecules interlink the sheets to form a unique three-dimensional supramolecular architecture.

AB - A hydrogen-bonded supramolecular compound, [H3cth][Fe(CN)6] • 3H2O, was synthesized from meso-5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane(cth) and K3 [Fe(CN)6]. The compound crystallizes in triclinic space group P1, with a=0. 930 97(9) nm, b=1.051 60(11) nm, c=1. 638 47(17) nm, α=101. 077(2)°, β=90. 860(2)°, γ=111. 671(2)°, V=1. 456 4(3) nm3, Z = 2, R=0. 041 5. The structure consists of neutral two-dimensional sheets assembled via hydrogen bonds between the partially protonated macrocyclic tetraamine and the hexacyanoferrate(double-struck I sign) ion, while the hydrogen bonds involving water molecules interlink the sheets to form a unique three-dimensional supramolecular architecture.

KW - Crystal structure

KW - Hydrogen bond

KW - Macrocyclic compound

KW - Supramolecule

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M3 - 文章

AN - SCOPUS:0345754955

SN - 0251-0790

VL - 21

SP - 666

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 5

ER -

Synthesis and Structure of a Three-dimensional Hydrogen-bonded Supramolecular Compound [H₃cth] [Fe(CN)₆] • 3H₂O

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