Synthesis and revision of stereochemistry of rubescensin S

Mei Zhang; Yangming Zhang; Wei Lu; Fa Jun Nan

doi:10.1039/c1ob05611e

Synthesis and revision of stereochemistry of rubescensin S

Mei Zhang
, Yangming Zhang
, Wei Lu^*
, Fa Jun Nan

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

An effective two step transformation of oridonin to 15,16-seco-ent-kaurane skeleton is reported. We also achieved the conversion of one intermediate to natural product rubescensin S and revised its structure as a 13S configuration although 13R is reported in the literature.

Original language	English
Pages (from-to)	4436-4439
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	9
Issue number	12
DOIs	https://doi.org/10.1039/c1ob05611e
State	Published - 21 Jun 2011

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title = "Synthesis and revision of stereochemistry of rubescensin S",

abstract = "An effective two step transformation of oridonin to 15,16-seco-ent-kaurane skeleton is reported. We also achieved the conversion of one intermediate to natural product rubescensin S and revised its structure as a 13S configuration although 13R is reported in the literature.",

author = "Mei Zhang and Yangming Zhang and Wei Lu and Nan, \{Fa Jun\}",

year = "2011",

month = jun,

day = "21",

doi = "10.1039/c1ob05611e",

language = "英语",

volume = "9",

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journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Synthesis and revision of stereochemistry of rubescensin S

AU - Zhang, Mei

AU - Zhang, Yangming

AU - Lu, Wei

AU - Nan, Fa Jun

PY - 2011/6/21

Y1 - 2011/6/21

N2 - An effective two step transformation of oridonin to 15,16-seco-ent-kaurane skeleton is reported. We also achieved the conversion of one intermediate to natural product rubescensin S and revised its structure as a 13S configuration although 13R is reported in the literature.

AB - An effective two step transformation of oridonin to 15,16-seco-ent-kaurane skeleton is reported. We also achieved the conversion of one intermediate to natural product rubescensin S and revised its structure as a 13S configuration although 13R is reported in the literature.

UR - https://www.scopus.com/pages/publications/79957979055

U2 - 10.1039/c1ob05611e

DO - 10.1039/c1ob05611e

M3 - 文章

C2 - 21584305

AN - SCOPUS:79957979055

SN - 1477-0520

VL - 9

SP - 4436

EP - 4439

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 12

ER -

Synthesis and revision of stereochemistry of rubescensin S

Abstract

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