Abstract
N,N′-bis(L-phenylalanyl)ethane-l,2-diamine was prepared by using L-phenylalanine and ethane-diamine. The synthetic process was improved. The ligand reacted with copper dichloride to form the chiral coordination compound. The single crystal was obtained in methanol solution. It is shown by X-ray structural studies that the crystal belongs to the tetragonal system and the space group is I4. The lattice parameters are as follows: a = 2.5044(4) nm, b = 2.5044(4) nm, c = 0.8707(3) nm, V = 5.461(2) nm3, Dc = 1.365 g/ cm3, Z = 8. In the structure of the complex, the Cu(II) cation is coordinated by two nitrogen atoms, two oxygen atoms and one chlorine atom.
| Original language | English |
|---|---|
| Pages (from-to) | 812-816 |
| Number of pages | 5 |
| Journal | Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities |
| Volume | 27 |
| Issue number | 5 |
| State | Published - May 2006 |
Keywords
- Bisamide
- Chiral complex
- Crystal structure
- Ethanediamine
- L-Phenylalanine