Synthesis and crystal structure of a tetramer chiral complex {[Cu(C20H26N4O2)Cl] Cl·4H2O}4

  • Yun Fei He*
  • , Min Qin Chen
  • , Li Yi Dai
  • , Gui Rong Zhang
  • , Qiang Li
  • , Lin Sheng Wang
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

N,N′-bis(L-phenylalanyl)ethane-l,2-diamine was prepared by using L-phenylalanine and ethane-diamine. The synthetic process was improved. The ligand reacted with copper dichloride to form the chiral coordination compound. The single crystal was obtained in methanol solution. It is shown by X-ray structural studies that the crystal belongs to the tetragonal system and the space group is I4. The lattice parameters are as follows: a = 2.5044(4) nm, b = 2.5044(4) nm, c = 0.8707(3) nm, V = 5.461(2) nm3, Dc = 1.365 g/ cm3, Z = 8. In the structure of the complex, the Cu(II) cation is coordinated by two nitrogen atoms, two oxygen atoms and one chlorine atom.

Original languageEnglish
Pages (from-to)812-816
Number of pages5
JournalKao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume27
Issue number5
StatePublished - May 2006

Keywords

  • Bisamide
  • Chiral complex
  • Crystal structure
  • Ethanediamine
  • L-Phenylalanine

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