Synthesis and crystal structure of a one-dimensional coordination polymer containing unusual Na2Cu2 tetrametallacyclic units

En Qing Gao; Hai Ying Sun; Dai Zheng Liao; Zong Hui Jiang; Shi Ping Yan

doi:10.1002/cjoc.20020200811

Synthesis and crystal structure of a one-dimensional coordination polymer containing unusual Na₂Cu₂ tetrametallacyclic units

En Qing Gao^*
, Hai Ying Sun
, Dai Zheng Liao
, Zong Hui Jiang
, Shi Ping Yan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A unique coordination polymer, {[CuLNa(CIO₄)] · H ₂O}_n (1), was isolated from the solution containing sodium perchlorate and the neutral macrocydic oxamidocopper(II) complex [CuL] (H ₂L = 2,3-dioxo-5, 6:13, 14-dibenzo-7, 12.bis(ethoxycarbonyl)-1, 4, 8, 11-tetraazacydotetradeca-7, 11-diene). The complex is composed of [Na ₂Cu₂] tetrametallacydes bridged by perchlorate ions to form infinite one-dimensional chains which are stacked via π-π interactions and weak coordination bonds to result in a two-dimensional supramolecular network. The perclorate ions were found to coordinate to sodium atoms in the unusual bridging chelating tridentate mode of μ₂-(O: O′, O″).

Original language	English
Pages (from-to)	766-770
Number of pages	5
Journal	Chinese Journal of Chemistry
Volume	20
Issue number	8
DOIs	https://doi.org/10.1002/cjoc.20020200811
State	Published - Aug 2002
Externally published	Yes

Keywords

Coordination polymer
Crystal structure
Macrocyclic complex

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10.1002/cjoc.20020200811

Cite this

@article{d306fb3ace9343bebfddc06a8fbe0511,

title = "Synthesis and crystal structure of a one-dimensional coordination polymer containing unusual Na2Cu2 tetrametallacyclic units",

abstract = "A unique coordination polymer, \{[CuLNa(CIO4)] · H 2O\}n (1), was isolated from the solution containing sodium perchlorate and the neutral macrocydic oxamidocopper(II) complex [CuL] (H 2L = 2,3-dioxo-5, 6:13, 14-dibenzo-7, 12.bis(ethoxycarbonyl)-1, 4, 8, 11-tetraazacydotetradeca-7, 11-diene). The complex is composed of [Na 2Cu2] tetrametallacydes bridged by perchlorate ions to form infinite one-dimensional chains which are stacked via π-π interactions and weak coordination bonds to result in a two-dimensional supramolecular network. The perclorate ions were found to coordinate to sodium atoms in the unusual bridging chelating tridentate mode of μ2-(O: O′, O″).",

keywords = "Coordination polymer, Crystal structure, Macrocyclic complex",

author = "Gao, \{En Qing\} and Sun, \{Hai Ying\} and Liao, \{Dai Zheng\} and Jiang, \{Zong Hui\} and Yan, \{Shi Ping\}",

year = "2002",

month = aug,

doi = "10.1002/cjoc.20020200811",

language = "英语",

volume = "20",

pages = "766--770",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley and Sons Inc",

number = "8",

}

TY - JOUR

T1 - Synthesis and crystal structure of a one-dimensional coordination polymer containing unusual Na2Cu2 tetrametallacyclic units

AU - Gao, En Qing

AU - Sun, Hai Ying

AU - Liao, Dai Zheng

AU - Jiang, Zong Hui

AU - Yan, Shi Ping

PY - 2002/8

Y1 - 2002/8

N2 - A unique coordination polymer, {[CuLNa(CIO4)] · H 2O}n (1), was isolated from the solution containing sodium perchlorate and the neutral macrocydic oxamidocopper(II) complex [CuL] (H 2L = 2,3-dioxo-5, 6:13, 14-dibenzo-7, 12.bis(ethoxycarbonyl)-1, 4, 8, 11-tetraazacydotetradeca-7, 11-diene). The complex is composed of [Na 2Cu2] tetrametallacydes bridged by perchlorate ions to form infinite one-dimensional chains which are stacked via π-π interactions and weak coordination bonds to result in a two-dimensional supramolecular network. The perclorate ions were found to coordinate to sodium atoms in the unusual bridging chelating tridentate mode of μ2-(O: O′, O″).

AB - A unique coordination polymer, {[CuLNa(CIO4)] · H 2O}n (1), was isolated from the solution containing sodium perchlorate and the neutral macrocydic oxamidocopper(II) complex [CuL] (H 2L = 2,3-dioxo-5, 6:13, 14-dibenzo-7, 12.bis(ethoxycarbonyl)-1, 4, 8, 11-tetraazacydotetradeca-7, 11-diene). The complex is composed of [Na 2Cu2] tetrametallacydes bridged by perchlorate ions to form infinite one-dimensional chains which are stacked via π-π interactions and weak coordination bonds to result in a two-dimensional supramolecular network. The perclorate ions were found to coordinate to sodium atoms in the unusual bridging chelating tridentate mode of μ2-(O: O′, O″).

KW - Coordination polymer

KW - Crystal structure

KW - Macrocyclic complex

UR - https://www.scopus.com/pages/publications/24944480116

U2 - 10.1002/cjoc.20020200811

DO - 10.1002/cjoc.20020200811

M3 - 文章

AN - SCOPUS:24944480116

SN - 1001-604X

VL - 20

SP - 766

EP - 770

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 8

ER -

Synthesis and crystal structure of a one-dimensional coordination polymer containing unusual Na₂Cu₂ tetrametallacyclic units

Abstract

Keywords

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