Synthesis and Crystal Structure of 1, 3, 5, 7-tetramethyl-2, 6, 8-triethyl Pyrromethene-BF2 Complex

Yi Zhong Yuan; Zu Guang Yao; Zhen Rong Sun; He Ping Zeng; Jing Xin Ding; Da De Zhang

Synthesis and Crystal Structure of 1, 3, 5, 7-tetramethyl-2, 6, 8-triethyl Pyrromethene-BF₂ Complex

Yi Zhong Yuan^*
, Zu Guang Yao
, Zhen Rong Sun
, He Ping Zeng
, Jing Xin Ding
, Da De Zhang

^*Corresponding author for this work

East China University of Science and Technology
East China Normal University
Res. Inst. Photo. Mat. Chem. Indust.

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound (C₁₉H₂₇BF₂N₂,M_r = 332.24) was obtained by the reaction of 2,4-dimethyl-3-ethylpyrrole with triethylamine and boron trifluoride diethyl etherate in dichloroethane. Its structure was characterized by elemental analysis, IR, ¹H NMR,MS and X-ray diffraction.The crystal of title compound belongs to tridinic system with space group P^-₁ (No.2) and cell parameters: a = 1.225 7(2), b = 1.783 0(8), c = 0.887 7(2) nm, α = 100.26(2), β = 107.57(1), γ = 76.96(2)°, V = 1.789 2(9) nm³, M_r = 332.24, Z = 4, D_c = 1.233 g·cm^-3, μ(MoKα) = 0.86 cm^-1, F(000) = 712.00. R = 0.051, R_w = 0.060. In the molecule, all non-H atoms except C(12),C(15),C(18),F(1),F(2) are on the same plane. Based on its crystal data, we have also discussed the relationship between structure and property of title compound.

Original language	English
Pages (from-to)	265-266
Number of pages	2
Journal	Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
Volume	22
Issue number	2
State	Published - Apr 2002
Externally published	Yes

Keywords

Crystal structure
Pyrromethene-BF complexes
Synthesis

Cite this

@article{dddad40555f642aca6e78f390f02eddb,

title = "Synthesis and Crystal Structure of 1, 3, 5, 7-tetramethyl-2, 6, 8-triethyl Pyrromethene-BF2 Complex",

abstract = "The title compound (C19H27BF2N2,Mr = 332.24) was obtained by the reaction of 2,4-dimethyl-3-ethylpyrrole with triethylamine and boron trifluoride diethyl etherate in dichloroethane. Its structure was characterized by elemental analysis, IR, 1H NMR,MS and X-ray diffraction.The crystal of title compound belongs to tridinic system with space group P-1 (No.2) and cell parameters: a = 1.225 7(2), b = 1.783 0(8), c = 0.887 7(2) nm, α = 100.26(2), β = 107.57(1), γ = 76.96(2)°, V = 1.789 2(9) nm3, Mr = 332.24, Z = 4, Dc = 1.233 g·cm-3, μ(MoKα) = 0.86 cm-1, F(000) = 712.00. R = 0.051, Rw = 0.060. In the molecule, all non-H atoms except C(12),C(15),C(18),F(1),F(2) are on the same plane. Based on its crystal data, we have also discussed the relationship between structure and property of title compound.",

keywords = "Crystal structure, Pyrromethene-BF complexes, Synthesis",

author = "Yuan, \{Yi Zhong\} and Yao, \{Zu Guang\} and Sun, \{Zhen Rong\} and Zeng, \{He Ping\} and Ding, \{Jing Xin\} and Zhang, \{Da De\}",

year = "2002",

month = apr,

language = "英语",

volume = "22",

pages = "265--266",

journal = "Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis",

issn = "1000-0593",

publisher = "Editorial Office of Spectroscopy and Spectral Analysis",

number = "2",

}

TY - JOUR

T1 - Synthesis and Crystal Structure of 1, 3, 5, 7-tetramethyl-2, 6, 8-triethyl Pyrromethene-BF2 Complex

AU - Yuan, Yi Zhong

AU - Yao, Zu Guang

AU - Sun, Zhen Rong

AU - Zeng, He Ping

AU - Ding, Jing Xin

AU - Zhang, Da De

PY - 2002/4

Y1 - 2002/4

N2 - The title compound (C19H27BF2N2,Mr = 332.24) was obtained by the reaction of 2,4-dimethyl-3-ethylpyrrole with triethylamine and boron trifluoride diethyl etherate in dichloroethane. Its structure was characterized by elemental analysis, IR, 1H NMR,MS and X-ray diffraction.The crystal of title compound belongs to tridinic system with space group P-1 (No.2) and cell parameters: a = 1.225 7(2), b = 1.783 0(8), c = 0.887 7(2) nm, α = 100.26(2), β = 107.57(1), γ = 76.96(2)°, V = 1.789 2(9) nm3, Mr = 332.24, Z = 4, Dc = 1.233 g·cm-3, μ(MoKα) = 0.86 cm-1, F(000) = 712.00. R = 0.051, Rw = 0.060. In the molecule, all non-H atoms except C(12),C(15),C(18),F(1),F(2) are on the same plane. Based on its crystal data, we have also discussed the relationship between structure and property of title compound.

AB - The title compound (C19H27BF2N2,Mr = 332.24) was obtained by the reaction of 2,4-dimethyl-3-ethylpyrrole with triethylamine and boron trifluoride diethyl etherate in dichloroethane. Its structure was characterized by elemental analysis, IR, 1H NMR,MS and X-ray diffraction.The crystal of title compound belongs to tridinic system with space group P-1 (No.2) and cell parameters: a = 1.225 7(2), b = 1.783 0(8), c = 0.887 7(2) nm, α = 100.26(2), β = 107.57(1), γ = 76.96(2)°, V = 1.789 2(9) nm3, Mr = 332.24, Z = 4, Dc = 1.233 g·cm-3, μ(MoKα) = 0.86 cm-1, F(000) = 712.00. R = 0.051, Rw = 0.060. In the molecule, all non-H atoms except C(12),C(15),C(18),F(1),F(2) are on the same plane. Based on its crystal data, we have also discussed the relationship between structure and property of title compound.

KW - Crystal structure

KW - Pyrromethene-BF complexes

KW - Synthesis

UR - https://www.scopus.com/pages/publications/0347305891

M3 - 文章

AN - SCOPUS:0347305891

SN - 1000-0593

VL - 22

SP - 265

EP - 266

JO - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

JF - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

IS - 2

ER -

Synthesis and Crystal Structure of 1, 3, 5, 7-tetramethyl-2, 6, 8-triethyl Pyrromethene-BF₂ Complex

Abstract

Keywords

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