Synthesis and characterization of novel mesogen-jacketed liquid crystalline miktoarm star rod-coil block copolymer

Jianfang Chen; Xingzhu Wang; Xiaojuan Liao; Hailiang Zhang; Xiayu Wang; Qifeng Zhou

doi:10.1002/marc.200500605

Synthesis and characterization of novel mesogen-jacketed liquid crystalline miktoarm star rod-coil block copolymer

Jianfang Chen
, Xingzhu Wang
, Xiaojuan Liao
, Hailiang Zhang^*
, Xiayu Wang
, Qifeng Zhou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A series of novel mesogen-jacketed liquid crystal miktoarm star rod-coil block copolymers were synthesized via atom transfer radical polymerization (ATRP). Their architectures {coil conformation of styrene segment and rigid rod conformation of {2,5-bis[(4-methoxyphenyl)oxycarbonyljstyrene) (MFCS) segment} were confirmed by OPC, ¹H NMR, and MALDI-TOF studies. The liquid crystalline behaviors of the synthesized copolymers are evidenced from POM observation. The liquid crystalline phase depends on the molecular weights of the rigid rod arm of miktoarm star copolymers.

Original language	English
Pages (from-to)	51-56
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	27
Issue number	1
DOIs	https://doi.org/10.1002/marc.200500605
State	Published - 3 Jan 2006
Externally published	Yes

Keywords

Atom transfer radical polymerization (ATRP)
Mesogen-jacketed liquid crystal polymer
Miktoarm star copolymer
Rod-coil block copolymer

Access to Document

10.1002/marc.200500605

Cite this

@article{8170f3e98fa84550bbeb4b56d69583cb,

title = "Synthesis and characterization of novel mesogen-jacketed liquid crystalline miktoarm star rod-coil block copolymer",

abstract = "A series of novel mesogen-jacketed liquid crystal miktoarm star rod-coil block copolymers were synthesized via atom transfer radical polymerization (ATRP). Their architectures \{coil conformation of styrene segment and rigid rod conformation of \{2,5-bis[(4-methoxyphenyl)oxycarbonyljstyrene) (MFCS) segment\} were confirmed by OPC, 1H NMR, and MALDI-TOF studies. The liquid crystalline behaviors of the synthesized copolymers are evidenced from POM observation. The liquid crystalline phase depends on the molecular weights of the rigid rod arm of miktoarm star copolymers.",

keywords = "Atom transfer radical polymerization (ATRP), Mesogen-jacketed liquid crystal polymer, Miktoarm star copolymer, Rod-coil block copolymer",

author = "Jianfang Chen and Xingzhu Wang and Xiaojuan Liao and Hailiang Zhang and Xiayu Wang and Qifeng Zhou",

year = "2006",

month = jan,

day = "3",

doi = "10.1002/marc.200500605",

language = "英语",

volume = "27",

pages = "51--56",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

publisher = "Wiley-VCH Verlag",

number = "1",

}

TY - JOUR

T1 - Synthesis and characterization of novel mesogen-jacketed liquid crystalline miktoarm star rod-coil block copolymer

AU - Chen, Jianfang

AU - Wang, Xingzhu

AU - Liao, Xiaojuan

AU - Zhang, Hailiang

AU - Wang, Xiayu

AU - Zhou, Qifeng

PY - 2006/1/3

Y1 - 2006/1/3

N2 - A series of novel mesogen-jacketed liquid crystal miktoarm star rod-coil block copolymers were synthesized via atom transfer radical polymerization (ATRP). Their architectures {coil conformation of styrene segment and rigid rod conformation of {2,5-bis[(4-methoxyphenyl)oxycarbonyljstyrene) (MFCS) segment} were confirmed by OPC, 1H NMR, and MALDI-TOF studies. The liquid crystalline behaviors of the synthesized copolymers are evidenced from POM observation. The liquid crystalline phase depends on the molecular weights of the rigid rod arm of miktoarm star copolymers.

AB - A series of novel mesogen-jacketed liquid crystal miktoarm star rod-coil block copolymers were synthesized via atom transfer radical polymerization (ATRP). Their architectures {coil conformation of styrene segment and rigid rod conformation of {2,5-bis[(4-methoxyphenyl)oxycarbonyljstyrene) (MFCS) segment} were confirmed by OPC, 1H NMR, and MALDI-TOF studies. The liquid crystalline behaviors of the synthesized copolymers are evidenced from POM observation. The liquid crystalline phase depends on the molecular weights of the rigid rod arm of miktoarm star copolymers.

KW - Atom transfer radical polymerization (ATRP)

KW - Mesogen-jacketed liquid crystal polymer

KW - Miktoarm star copolymer

KW - Rod-coil block copolymer

UR - https://www.scopus.com/pages/publications/30444446965

U2 - 10.1002/marc.200500605

DO - 10.1002/marc.200500605

M3 - 文章

AN - SCOPUS:30444446965

SN - 1022-1336

VL - 27

SP - 51

EP - 56

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 1

ER -

Synthesis and characterization of novel mesogen-jacketed liquid crystalline miktoarm star rod-coil block copolymer

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this