Synthesis and characterization of new Cu(II) and [CuII3MnII] complexes of macrocyclic oxamides

En Qing Gao; Guang Ming Yang; Zong Hui Jiang; Shi Ping Yan; Geng Lin Wang; Dai Zheng Liao

doi:10.1080/00945719909349510

Synthesis and characterization of new Cu(II) and [Cu^II₃Mn^II] complexes of macrocyclic oxamides

En Qing Gao, Guang Ming Yang, Zong Hui Jiang, Shi Ping Yan, Geng Lin Wang, Dai Zheng Liao

Nankai University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two new Cu(II) complexes of [14]N₄ and [15]N₄ macrocyclic oxamides, [CuL¹] and [CuL²] [L¹ and L² are the dianions of 2,3-dioxo-5,6:14,15-dibenzo-7,13-bis(ethoxycarbonyl)-1,4,8,12- tetraazacyclotetradeca-7,12-diene and 2,3-dioxo-5,6:9,10:13,14-tribenzo-7,12-bis(ethoxycarbonyl)-1,4,8,11- tetraazacyclotetradeca-7,11-diene, respectively], have been prepared by the template reactions of 2,2′-(oxalyldiimino)bis(phenylglyoxylate) with diamines and cupric acetate in the presence of triethylamine. Using the strategy of "complexes as ligands", two tetranuclear complexes of the formula [(CuL¹)₃Mn](ClO₄)₂ and [(CuL²)₃Mn](ClO₄)₂ have been synthesized. The complexes have been characterized by means of elemental analyses, IR and electronic spectra, conductivity and magnetic susceptibility measurements.

Original language	English
Pages (from-to)	1053-1061
Number of pages	9
Journal	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume	29
Issue number	6
DOIs	https://doi.org/10.1080/00945719909349510
State	Published - 1999
Externally published	Yes

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@article{2c4991cfdccc416795f93b9549669023,

title = "Synthesis and characterization of new Cu(II) and [CuII3MnII] complexes of macrocyclic oxamides",

abstract = "Two new Cu(II) complexes of [14]N4 and [15]N4 macrocyclic oxamides, [CuL1] and [CuL2] [L1 and L2 are the dianions of 2,3-dioxo-5,6:14,15-dibenzo-7,13-bis(ethoxycarbonyl)-1,4,8,12- tetraazacyclotetradeca-7,12-diene and 2,3-dioxo-5,6:9,10:13,14-tribenzo-7,12-bis(ethoxycarbonyl)-1,4,8,11- tetraazacyclotetradeca-7,11-diene, respectively], have been prepared by the template reactions of 2,2′-(oxalyldiimino)bis(phenylglyoxylate) with diamines and cupric acetate in the presence of triethylamine. Using the strategy of {"}complexes as ligands{"}, two tetranuclear complexes of the formula [(CuL1)3Mn](ClO4)2 and [(CuL2)3Mn](ClO4)2 have been synthesized. The complexes have been characterized by means of elemental analyses, IR and electronic spectra, conductivity and magnetic susceptibility measurements.",

author = "Gao, \{En Qing\} and Yang, \{Guang Ming\} and Jiang, \{Zong Hui\} and Yan, \{Shi Ping\} and Wang, \{Geng Lin\} and Liao, \{Dai Zheng\}",

year = "1999",

doi = "10.1080/00945719909349510",

language = "英语",

volume = "29",

pages = "1053--1061",

journal = "Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry",

issn = "0094-5714",

publisher = "Taylor and Francis Ltd.",

number = "6",

}

TY - JOUR

T1 - Synthesis and characterization of new Cu(II) and [CuII3MnII] complexes of macrocyclic oxamides

AU - Gao, En Qing

AU - Yang, Guang Ming

AU - Jiang, Zong Hui

AU - Yan, Shi Ping

AU - Wang, Geng Lin

AU - Liao, Dai Zheng

PY - 1999

Y1 - 1999

N2 - Two new Cu(II) complexes of [14]N4 and [15]N4 macrocyclic oxamides, [CuL1] and [CuL2] [L1 and L2 are the dianions of 2,3-dioxo-5,6:14,15-dibenzo-7,13-bis(ethoxycarbonyl)-1,4,8,12- tetraazacyclotetradeca-7,12-diene and 2,3-dioxo-5,6:9,10:13,14-tribenzo-7,12-bis(ethoxycarbonyl)-1,4,8,11- tetraazacyclotetradeca-7,11-diene, respectively], have been prepared by the template reactions of 2,2′-(oxalyldiimino)bis(phenylglyoxylate) with diamines and cupric acetate in the presence of triethylamine. Using the strategy of "complexes as ligands", two tetranuclear complexes of the formula [(CuL1)3Mn](ClO4)2 and [(CuL2)3Mn](ClO4)2 have been synthesized. The complexes have been characterized by means of elemental analyses, IR and electronic spectra, conductivity and magnetic susceptibility measurements.

AB - Two new Cu(II) complexes of [14]N4 and [15]N4 macrocyclic oxamides, [CuL1] and [CuL2] [L1 and L2 are the dianions of 2,3-dioxo-5,6:14,15-dibenzo-7,13-bis(ethoxycarbonyl)-1,4,8,12- tetraazacyclotetradeca-7,12-diene and 2,3-dioxo-5,6:9,10:13,14-tribenzo-7,12-bis(ethoxycarbonyl)-1,4,8,11- tetraazacyclotetradeca-7,11-diene, respectively], have been prepared by the template reactions of 2,2′-(oxalyldiimino)bis(phenylglyoxylate) with diamines and cupric acetate in the presence of triethylamine. Using the strategy of "complexes as ligands", two tetranuclear complexes of the formula [(CuL1)3Mn](ClO4)2 and [(CuL2)3Mn](ClO4)2 have been synthesized. The complexes have been characterized by means of elemental analyses, IR and electronic spectra, conductivity and magnetic susceptibility measurements.

UR - https://www.scopus.com/pages/publications/0033423046

U2 - 10.1080/00945719909349510

DO - 10.1080/00945719909349510

M3 - 文章

AN - SCOPUS:0033423046

SN - 0094-5714

VL - 29

SP - 1053

EP - 1061

JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

IS - 6

ER -

Synthesis and characterization of new Cu(II) and [Cu^II₃Mn^II] complexes of macrocyclic oxamides

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