Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesquioxane

Han ming DING; Da wei ZHANG; Jiang LI; Ai guo KONG; Yong kui SHAN

doi:10.1016/S1005-9040(07)60083-X

Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesquioxane

Han ming DING, Da wei ZHANG, Jiang LI, Ai guo KONG, Yong kui SHAN^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl₄ ethanol solution as precursors. The product was characterized by FTIR, ²⁹Si NMR, UV-Vis, and XRD. Structural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligosilsesquioxane as building blocks and titanium as bridging atoms.

Original language	English
Pages (from-to)	388-390
Number of pages	3
Journal	Chemical Research in Chinese Universities
Volume	23
Issue number	4
DOIs	https://doi.org/10.1016/S1005-9040(07)60083-X
State	Published - Jul 2007

Keywords

Polyhedral oligosilsesquioxane
Synthesis
Titanium-silicate material

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10.1016/S1005-9040(07)60083-X

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title = "Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesquioxane",

abstract = "A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, 29Si NMR, UV-Vis, and XRD. Structural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligosilsesquioxane as building blocks and titanium as bridging atoms.",

keywords = "Polyhedral oligosilsesquioxane, Synthesis, Titanium-silicate material",

author = "DING, \{Han ming\} and ZHANG, \{Da wei\} and Jiang LI and KONG, \{Ai guo\} and SHAN, \{Yong kui\}",

year = "2007",

month = jul,

doi = "10.1016/S1005-9040(07)60083-X",

language = "英语",

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T1 - Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesquioxane

AU - DING, Han ming

AU - ZHANG, Da wei

AU - LI, Jiang

AU - KONG, Ai guo

AU - SHAN, Yong kui

PY - 2007/7

Y1 - 2007/7

N2 - A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, 29Si NMR, UV-Vis, and XRD. Structural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligosilsesquioxane as building blocks and titanium as bridging atoms.

AB - A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, 29Si NMR, UV-Vis, and XRD. Structural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligosilsesquioxane as building blocks and titanium as bridging atoms.

KW - Polyhedral oligosilsesquioxane

KW - Synthesis

KW - Titanium-silicate material

UR - https://www.scopus.com/pages/publications/56449085432

U2 - 10.1016/S1005-9040(07)60083-X

DO - 10.1016/S1005-9040(07)60083-X

M3 - 文章

AN - SCOPUS:56449085432

SN - 1005-9040

VL - 23

SP - 388

EP - 390

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 4

ER -

Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesquioxane

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Keywords

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