Synthesis and anion recognition properties of two novel tetraamide calix[4](aza)crowns for optical anion sensor

Ling Zhi Meng; Gong Xiong Mei; Yong Bing He; Zhen Ya Zeng; Shun Ying Liu

Synthesis and anion recognition properties of two novel tetraamide calix[4](aza)crowns for optical anion sensor

Ling Zhi Meng^*
, Gong Xiong Mei
, Yong Bing He
, Zhen Ya Zeng
, Shun Ying Liu

^*Corresponding author for this work

Wuhan University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Two new tetraamide calix[4](aza)crowns (5a, 5b) were synthesized and used for optical anion sensors. Addition of host 5a or 5b to the p-NO ₂C₆H₄O^- anion in CHCl₃ resulted in decreasing absorption of band at 423 nm and the yellow solution of p-NO₂C₆H₄O^- anion became colorless because of the formation of host-guest complexes between host 5a or 5b and p-NO₂C₆H₄O^-. The fluorescence response was observed in the presence of anions such as p-NO₂C ₆H₄O^-, F^-, H₂PO ₄^-, and the receptors 5a and 5b were highly selective toward p-NO₂C₆H₄O^-. The degree of change in the emission intensity was in the order of p-NO₂C ₆H₄O^->F^->H₂PO ₄^-≫Cl^-, Br^-, I^-. The fluorescence spectroscopy titration experiments indicated the formation of a 1:1 stoichiometry complex between receptor 5a (or 5b) and anion by nonlinear fitting curve.

Original language	English
Pages (from-to)	416-420
Number of pages	5
Journal	Acta Chimica Sinica
Volume	63
Issue number	5
State	Published - 2005
Externally published	Yes

Keywords

Anion recognition
Fluorescence
Sensing
Synthesis
Tetraamide calix[4](aza)crown

Cite this

@article{38ceede53f8c48708ab814f20a35ba56,

title = "Synthesis and anion recognition properties of two novel tetraamide calix[4](aza)crowns for optical anion sensor",

abstract = "Two new tetraamide calix[4](aza)crowns (5a, 5b) were synthesized and used for optical anion sensors. Addition of host 5a or 5b to the p-NO 2C6H4O- anion in CHCl3 resulted in decreasing absorption of band at 423 nm and the yellow solution of p-NO2C6H4O- anion became colorless because of the formation of host-guest complexes between host 5a or 5b and p-NO2C6H4O-. The fluorescence response was observed in the presence of anions such as p-NO2C 6H4O-, F-, H2PO 4-, and the receptors 5a and 5b were highly selective toward p-NO2C6H4O-. The degree of change in the emission intensity was in the order of p-NO2C 6H4O->F->H2PO 4-≫Cl-, Br-, I-. The fluorescence spectroscopy titration experiments indicated the formation of a 1:1 stoichiometry complex between receptor 5a (or 5b) and anion by nonlinear fitting curve.",

keywords = "Anion recognition, Fluorescence, Sensing, Synthesis, Tetraamide calix[4](aza)crown",

author = "Meng, \{Ling Zhi\} and Mei, \{Gong Xiong\} and He, \{Yong Bing\} and Zeng, \{Zhen Ya\} and Liu, \{Shun Ying\}",

year = "2005",

language = "英语",

volume = "63",

pages = "416--420",

journal = "Acta Chimica Sinica",

issn = "0567-7351",

publisher = "Editorial Office of Acta Chimica Sinica",

number = "5",

}

TY - JOUR

T1 - Synthesis and anion recognition properties of two novel tetraamide calix[4](aza)crowns for optical anion sensor

AU - Meng, Ling Zhi

AU - Mei, Gong Xiong

AU - He, Yong Bing

AU - Zeng, Zhen Ya

AU - Liu, Shun Ying

PY - 2005

Y1 - 2005

N2 - Two new tetraamide calix[4](aza)crowns (5a, 5b) were synthesized and used for optical anion sensors. Addition of host 5a or 5b to the p-NO 2C6H4O- anion in CHCl3 resulted in decreasing absorption of band at 423 nm and the yellow solution of p-NO2C6H4O- anion became colorless because of the formation of host-guest complexes between host 5a or 5b and p-NO2C6H4O-. The fluorescence response was observed in the presence of anions such as p-NO2C 6H4O-, F-, H2PO 4-, and the receptors 5a and 5b were highly selective toward p-NO2C6H4O-. The degree of change in the emission intensity was in the order of p-NO2C 6H4O->F->H2PO 4-≫Cl-, Br-, I-. The fluorescence spectroscopy titration experiments indicated the formation of a 1:1 stoichiometry complex between receptor 5a (or 5b) and anion by nonlinear fitting curve.

AB - Two new tetraamide calix[4](aza)crowns (5a, 5b) were synthesized and used for optical anion sensors. Addition of host 5a or 5b to the p-NO 2C6H4O- anion in CHCl3 resulted in decreasing absorption of band at 423 nm and the yellow solution of p-NO2C6H4O- anion became colorless because of the formation of host-guest complexes between host 5a or 5b and p-NO2C6H4O-. The fluorescence response was observed in the presence of anions such as p-NO2C 6H4O-, F-, H2PO 4-, and the receptors 5a and 5b were highly selective toward p-NO2C6H4O-. The degree of change in the emission intensity was in the order of p-NO2C 6H4O->F->H2PO 4-≫Cl-, Br-, I-. The fluorescence spectroscopy titration experiments indicated the formation of a 1:1 stoichiometry complex between receptor 5a (or 5b) and anion by nonlinear fitting curve.

KW - Anion recognition

KW - Fluorescence

KW - Sensing

KW - Synthesis

KW - Tetraamide calix[4](aza)crown

UR - https://www.scopus.com/pages/publications/33749002158

M3 - 文章

AN - SCOPUS:33749002158

SN - 0567-7351

VL - 63

SP - 416

EP - 420

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

IS - 5

ER -

Synthesis and anion recognition properties of two novel tetraamide calix[4](aza)crowns for optical anion sensor

Abstract

Keywords

Other files and links

Fingerprint

Cite this