Syntheses of novel zinc organic complexes [Zn(C22H 12N6)2](C3H9N)(NO 3)2·H2O and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) under solvothermal conditions

J. Hu; O. Gao; J. Shi

doi:10.1016/s0167-2991(04)80594-9

Syntheses of novel zinc organic complexes [Zn(C₂₂H ₁₂N₆)₂](C₃H₉N)(NO ₃)₂·H₂O and [Zn(CH₃COO) ₂(C₂₂H₁₂N₆)] (C₃H ₉N) under solvothermal conditions

J. Hu
, O. Gao^*
, J. Shi

^*Corresponding author for this work

CAS - Shanghai Institute of Ceramics

Research output: Contribution to journal › Article › peer-review

Abstract

Two novel kinds of compounds [Zn(C₂₂H₁₂N ₆)₂](C₃H₉N)(NO₃) ₂·H₂O (I) and [Zn(CH₃COO) ₂(C₂₂H₁₂N₆)] (C₃H ₉N) (II) have been synthesized under solvothermal conditions with the original chemical molar ratios of 1.0Zn(NO₃)₂· 6H₂O: 170CH₃CH₂OH: 2.0C₂₂H ₁₂N₆: 140CHCl₃: 0.5C₃H₁₀N and 1.0Zn(CH₃COO)₂·6H₂O: 94CH ₃CH₂OH: 2.0C₂₂H₁₂N₆: 186CHCl₃: 1.0C₃H₁₀N, respectively. The two compounds have been characterized by XRD, FT-IR, Raman, SEM, UV-vis, and TG-DSC, etc. XRD analyses showed that the samples I and II were two kinds of novel materials with the largest d values of 12.03 and 10.06 Å, respectively. SEM images showed that the two samples were pure with hexagonal prism-like crystals. IR, Raman, and UV-vis spectra analyses for the two kinds of samples proved that the ligand 4,5-diazafluren-9-one-N₂ (C₂₂H ₁₂N₆, L) was coordinated with Zn²⁺ ion. TG-DSC analyses showed that both of the two samples were stable up to 400°C and then totally decomposed to ZnO over 1000°C.

Original language	English
Pages (from-to)	3074-3080
Number of pages	7
Journal	Studies in Surface Science and Catalysis
Volume	154 C
DOIs	https://doi.org/10.1016/s0167-2991(04)80594-9
State	Published - 2004
Externally published	Yes

Keywords

Characterization
Ligand 4,5-diazafluren-9-one-N
Stability
Zn organic complexes

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10.1016/s0167-2991(04)80594-9

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@article{81f060ea44a64293979d28e9e193b290,

title = "Syntheses of novel zinc organic complexes [Zn(C22H 12N6)2](C3H9N)(NO 3)2·H2O and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) under solvothermal conditions",

abstract = "Two novel kinds of compounds [Zn(C22H12N 6)2](C3H9N)(NO3) 2·H2O (I) and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) (II) have been synthesized under solvothermal conditions with the original chemical molar ratios of 1.0Zn(NO3)2· 6H2O: 170CH3CH2OH: 2.0C22H 12N6: 140CHCl3: 0.5C3H10N and 1.0Zn(CH3COO)2·6H2O: 94CH 3CH2OH: 2.0C22H12N6: 186CHCl3: 1.0C3H10N, respectively. The two compounds have been characterized by XRD, FT-IR, Raman, SEM, UV-vis, and TG-DSC, etc. XRD analyses showed that the samples I and II were two kinds of novel materials with the largest d values of 12.03 and 10.06 {\AA}, respectively. SEM images showed that the two samples were pure with hexagonal prism-like crystals. IR, Raman, and UV-vis spectra analyses for the two kinds of samples proved that the ligand 4,5-diazafluren-9-one-N2 (C22H 12N6, L) was coordinated with Zn2+ ion. TG-DSC analyses showed that both of the two samples were stable up to 400°C and then totally decomposed to ZnO over 1000°C.",

keywords = "Characterization, Ligand 4,5-diazafluren-9-one-N, Stability, Zn organic complexes",

author = "J. Hu and O. Gao and J. Shi",

year = "2004",

doi = "10.1016/s0167-2991(04)80594-9",

language = "英语",

volume = "154 C",

pages = "3074--3080",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier Inc.",

}

TY - JOUR

T1 - Syntheses of novel zinc organic complexes [Zn(C22H 12N6)2](C3H9N)(NO 3)2·H2O and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) under solvothermal conditions

AU - Hu, J.

AU - Gao, O.

AU - Shi, J.

PY - 2004

Y1 - 2004

N2 - Two novel kinds of compounds [Zn(C22H12N 6)2](C3H9N)(NO3) 2·H2O (I) and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) (II) have been synthesized under solvothermal conditions with the original chemical molar ratios of 1.0Zn(NO3)2· 6H2O: 170CH3CH2OH: 2.0C22H 12N6: 140CHCl3: 0.5C3H10N and 1.0Zn(CH3COO)2·6H2O: 94CH 3CH2OH: 2.0C22H12N6: 186CHCl3: 1.0C3H10N, respectively. The two compounds have been characterized by XRD, FT-IR, Raman, SEM, UV-vis, and TG-DSC, etc. XRD analyses showed that the samples I and II were two kinds of novel materials with the largest d values of 12.03 and 10.06 Å, respectively. SEM images showed that the two samples were pure with hexagonal prism-like crystals. IR, Raman, and UV-vis spectra analyses for the two kinds of samples proved that the ligand 4,5-diazafluren-9-one-N2 (C22H 12N6, L) was coordinated with Zn2+ ion. TG-DSC analyses showed that both of the two samples were stable up to 400°C and then totally decomposed to ZnO over 1000°C.

AB - Two novel kinds of compounds [Zn(C22H12N 6)2](C3H9N)(NO3) 2·H2O (I) and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) (II) have been synthesized under solvothermal conditions with the original chemical molar ratios of 1.0Zn(NO3)2· 6H2O: 170CH3CH2OH: 2.0C22H 12N6: 140CHCl3: 0.5C3H10N and 1.0Zn(CH3COO)2·6H2O: 94CH 3CH2OH: 2.0C22H12N6: 186CHCl3: 1.0C3H10N, respectively. The two compounds have been characterized by XRD, FT-IR, Raman, SEM, UV-vis, and TG-DSC, etc. XRD analyses showed that the samples I and II were two kinds of novel materials with the largest d values of 12.03 and 10.06 Å, respectively. SEM images showed that the two samples were pure with hexagonal prism-like crystals. IR, Raman, and UV-vis spectra analyses for the two kinds of samples proved that the ligand 4,5-diazafluren-9-one-N2 (C22H 12N6, L) was coordinated with Zn2+ ion. TG-DSC analyses showed that both of the two samples were stable up to 400°C and then totally decomposed to ZnO over 1000°C.

KW - Characterization

KW - Ligand 4,5-diazafluren-9-one-N

KW - Stability

KW - Zn organic complexes

UR - https://www.scopus.com/pages/publications/11844298991

U2 - 10.1016/s0167-2991(04)80594-9

DO - 10.1016/s0167-2991(04)80594-9

M3 - 文章

AN - SCOPUS:11844298991

SN - 0167-2991

VL - 154 C

SP - 3074

EP - 3080

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Syntheses of novel zinc organic complexes [Zn(C₂₂H ₁₂N₆)₂](C₃H₉N)(NO ₃)₂·H₂O and [Zn(CH₃COO) ₂(C₂₂H₁₂N₆)] (C₃H ₉N) under solvothermal conditions

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Keywords

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