TY - JOUR
T1 - Syntheses of novel zinc organic complexes [Zn(C22H 12N6)2](C3H9N)(NO 3)2·H2O and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) under solvothermal conditions
AU - Hu, J.
AU - Gao, O.
AU - Shi, J.
PY - 2004
Y1 - 2004
N2 - Two novel kinds of compounds [Zn(C22H12N 6)2](C3H9N)(NO3) 2·H2O (I) and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) (II) have been synthesized under solvothermal conditions with the original chemical molar ratios of 1.0Zn(NO3)2· 6H2O: 170CH3CH2OH: 2.0C22H 12N6: 140CHCl3: 0.5C3H10N and 1.0Zn(CH3COO)2·6H2O: 94CH 3CH2OH: 2.0C22H12N6: 186CHCl3: 1.0C3H10N, respectively. The two compounds have been characterized by XRD, FT-IR, Raman, SEM, UV-vis, and TG-DSC, etc. XRD analyses showed that the samples I and II were two kinds of novel materials with the largest d values of 12.03 and 10.06 Å, respectively. SEM images showed that the two samples were pure with hexagonal prism-like crystals. IR, Raman, and UV-vis spectra analyses for the two kinds of samples proved that the ligand 4,5-diazafluren-9-one-N2 (C22H 12N6, L) was coordinated with Zn2+ ion. TG-DSC analyses showed that both of the two samples were stable up to 400°C and then totally decomposed to ZnO over 1000°C.
AB - Two novel kinds of compounds [Zn(C22H12N 6)2](C3H9N)(NO3) 2·H2O (I) and [Zn(CH3COO) 2(C22H12N6)] (C3H 9N) (II) have been synthesized under solvothermal conditions with the original chemical molar ratios of 1.0Zn(NO3)2· 6H2O: 170CH3CH2OH: 2.0C22H 12N6: 140CHCl3: 0.5C3H10N and 1.0Zn(CH3COO)2·6H2O: 94CH 3CH2OH: 2.0C22H12N6: 186CHCl3: 1.0C3H10N, respectively. The two compounds have been characterized by XRD, FT-IR, Raman, SEM, UV-vis, and TG-DSC, etc. XRD analyses showed that the samples I and II were two kinds of novel materials with the largest d values of 12.03 and 10.06 Å, respectively. SEM images showed that the two samples were pure with hexagonal prism-like crystals. IR, Raman, and UV-vis spectra analyses for the two kinds of samples proved that the ligand 4,5-diazafluren-9-one-N2 (C22H 12N6, L) was coordinated with Zn2+ ion. TG-DSC analyses showed that both of the two samples were stable up to 400°C and then totally decomposed to ZnO over 1000°C.
KW - Characterization
KW - Ligand 4,5-diazafluren-9-one-N
KW - Stability
KW - Zn organic complexes
UR - https://www.scopus.com/pages/publications/11844298991
U2 - 10.1016/s0167-2991(04)80594-9
DO - 10.1016/s0167-2991(04)80594-9
M3 - 文章
AN - SCOPUS:11844298991
SN - 0167-2991
VL - 154 C
SP - 3074
EP - 3080
JO - Studies in Surface Science and Catalysis
JF - Studies in Surface Science and Catalysis
ER -