Surface and Catalytic Chemistry of Organoactinldes. Evidence for Surface-Stabilized Alkylidenes

Ming Yuan He; Robert L. Burwell; Tobin J. Marks

doi:10.1021/om00076a023

Surface and Catalytic Chemistry of Organoactinldes. Evidence for Surface-Stabilized Alkylidenes

Ming Yuan He
, Robert L. Burwell^*
, Tobin J. Marks

^*Corresponding author for this work

Northwestern University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The reaction of M[η⁵-(CH₃)₅C₅]₂(CH₃)₂ and [η⁵-(CH₃)₅C₅]₂(CD₃)₂ compounds, M = Th and U, with partially dehydroxylated and nearly completely dehydroxylated alumina yields methane via protolysis by surface OH, ring H atom abstraction, and elimination within the M(CH₃)₂ groups. The latter pathway is proposed on the basis of chemical evidence to result in alumina-stabilized actinide alkylidenes.

Original language	English
Pages (from-to)	566-569
Number of pages	4
Journal	Organometallics
Volume	2
Issue number	4
DOIs	https://doi.org/10.1021/om00076a023
State	Published - Apr 1983
Externally published	Yes

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title = "Surface and Catalytic Chemistry of Organoactinldes. Evidence for Surface-Stabilized Alkylidenes",

abstract = "The reaction of M[η5-(CH3)5C5]2(CH3)2 and [η5-(CH3)5C5]2(CD3)2 compounds, M = Th and U, with partially dehydroxylated and nearly completely dehydroxylated alumina yields methane via protolysis by surface OH, ring H atom abstraction, and elimination within the M(CH3)2 groups. The latter pathway is proposed on the basis of chemical evidence to result in alumina-stabilized actinide alkylidenes.",

author = "He, \{Ming Yuan\} and Burwell, \{Robert L.\} and Marks, \{Tobin J.\}",

year = "1983",

month = apr,

doi = "10.1021/om00076a023",

language = "英语",

volume = "2",

pages = "566--569",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Surface and Catalytic Chemistry of Organoactinldes. Evidence for Surface-Stabilized Alkylidenes

AU - He, Ming Yuan

AU - Burwell, Robert L.

AU - Marks, Tobin J.

PY - 1983/4

Y1 - 1983/4

N2 - The reaction of M[η5-(CH3)5C5]2(CH3)2 and [η5-(CH3)5C5]2(CD3)2 compounds, M = Th and U, with partially dehydroxylated and nearly completely dehydroxylated alumina yields methane via protolysis by surface OH, ring H atom abstraction, and elimination within the M(CH3)2 groups. The latter pathway is proposed on the basis of chemical evidence to result in alumina-stabilized actinide alkylidenes.

AB - The reaction of M[η5-(CH3)5C5]2(CH3)2 and [η5-(CH3)5C5]2(CD3)2 compounds, M = Th and U, with partially dehydroxylated and nearly completely dehydroxylated alumina yields methane via protolysis by surface OH, ring H atom abstraction, and elimination within the M(CH3)2 groups. The latter pathway is proposed on the basis of chemical evidence to result in alumina-stabilized actinide alkylidenes.

UR - https://www.scopus.com/pages/publications/0001127236

U2 - 10.1021/om00076a023

DO - 10.1021/om00076a023

M3 - 文章

AN - SCOPUS:0001127236

SN - 0276-7333

VL - 2

SP - 566

EP - 569

JO - Organometallics

JF - Organometallics

IS - 4

ER -

Surface and Catalytic Chemistry of Organoactinldes. Evidence for Surface-Stabilized Alkylidenes

Abstract

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