²²²Rn, ²¹⁰Pb and ²¹⁰Po in coastal zone groundwater: Activities, geochemical behaviors, consideration of seawater intrusion effect, and the potential radiation human-health risk

Groundwater quality in human-influenced coastal landscapes is receiving novel attention. Radionuclides have been recognized as another important monitoring indicator in many developed countries due to the discovery of extremely high level of natural ²¹⁰Po (up to 10,000 Bq/m³) and radium and radon isotopes. This study aims to evaluate the groundwater quality in the Beibu Bulf-Guangxi coast from radiological point of view. ²¹⁰Po, ²¹⁰Pb and ²²²Rn activities in 20 wells ranged from 0.24 ± 0.05 to 6.96 ± 1.62 Bq/m³, 2.17 ± 0.12 to 13.08 ± 0.74 Bq/m³ and 1500 ± 200 to 31,800 ± 900 Bq/m³, respectively. Compared with research data of other countries, groundwaters in this area have ²¹⁰Po, ²¹⁰Pb and ²²²Rn activity within low levels. The large deficiencies of ²¹⁰Po and ²¹⁰Pb relative to ²²²Rn in groundwaters implied that ²¹⁰Po and ²¹⁰Pb are strong particle-reactive radionuclides and they might be controlled by similar scavenging processes in groundwaters due to a good positive correlation between ²¹⁰Pb and ²¹⁰Po (R² = 0.67, p < 0.01). The concentrations of ²¹⁰Po and ²¹⁰Pb decreased with increasing pH values and salinity, which indicated that geochemical behaviors of ²¹⁰Po and ²¹⁰Pb in groundwater were influenced by seawater intrusion and pH changing. Groundwater ²²²Rn activity concentrations decreased with increasing salinity in coastal zone, which may be caused by dilution due to seawater intrusion or intensified ²²²Rn escaping from well-developed pores in coastal zone. The estimated annual ingestion doses for infants, children and adults were well below the recommended reference dose level (RDL) of 0.2–0.8 mSv/a, suggesting that consumption of analyzed groundwaters is safe from radiological point of view.