Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions

Yonghong Zhang; Yiming Li; Xiaomei Zhang; Xuefeng Jiang

doi:10.1039/c4cc08367a

Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions

Yonghong Zhang
, Yiming Li
, Xiaomei Zhang
, Xuefeng Jiang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

129 Scopus citations

Abstract

We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na₂S₂O₃ as a sulfurating reagent, CuSO₄ as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomolecules including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates.

Original language	English
Pages (from-to)	941-944
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	5
DOIs	https://doi.org/10.1039/c4cc08367a
State	Published - 18 Jan 2015

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title = "Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions",

abstract = "We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na2S2O3 as a sulfurating reagent, CuSO4 as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomolecules including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates.",

author = "Yonghong Zhang and Yiming Li and Xiaomei Zhang and Xuefeng Jiang",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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doi = "10.1039/c4cc08367a",

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T1 - Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions

AU - Zhang, Yonghong

AU - Li, Yiming

AU - Zhang, Xiaomei

AU - Jiang, Xuefeng

N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

PY - 2015/1/18

Y1 - 2015/1/18

N2 - We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na2S2O3 as a sulfurating reagent, CuSO4 as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomolecules including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates.

AB - We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na2S2O3 as a sulfurating reagent, CuSO4 as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomolecules including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates.

UR - https://www.scopus.com/pages/publications/84919683764

U2 - 10.1039/c4cc08367a

DO - 10.1039/c4cc08367a

M3 - 文章

C2 - 25435202

AN - SCOPUS:84919683764

SN - 1359-7345

VL - 51

SP - 941

EP - 944

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions

Abstract

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