Study on catalytic synthesis of 1,3-benzodioxoles by HY zeolite

Xuezheng Liang; Shan Gao; Jianguo Yang; Caihua Liu; Xinyu Yu; Mingyuan He

doi:10.1007/s11458-007-0007-7

Study on catalytic synthesis of 1,3-benzodioxoles by HY zeolite

Xuezheng Liang
, Shan Gao
, Jianguo Yang^*
, Caihua Liu
, Xinyu Yu
, Mingyuan He

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The acetalization and ketalization of various aldehydes and ketones with catechol by using HY zeolite as catalyst were studied. Effect of the reaction time, mole ratio of reactants, and amount of catalyst on the yield of benzodioxoles were investigated. Results show that HY is an efficient catalyst for the acetalization and ketalization with high conversion and selectivity in mild conditions. The best reaction conditions: molar ratio of catechol to aldehydes or ketones is 1:1.4, catalyst amount is 3.5 g/l mol catechol, reaction time is 5 h. Under these conditions, the conversion and selectivity were over 50% and 97%, respectively.

Original language	English
Pages (from-to)	31-34
Number of pages	4
Journal	Frontiers of Chemistry in China
Volume	2
Issue number	1
DOIs	https://doi.org/10.1007/s11458-007-0007-7
State	Published - Mar 2007

Keywords

Benzodioxoles
Catalyze
Condensation
HY zeolite
Synthesis

Access to Document

10.1007/s11458-007-0007-7

Cite this

@article{2427a1d308f240e191c93c5ba4434e2e,

title = "Study on catalytic synthesis of 1,3-benzodioxoles by HY zeolite",

abstract = "The acetalization and ketalization of various aldehydes and ketones with catechol by using HY zeolite as catalyst were studied. Effect of the reaction time, mole ratio of reactants, and amount of catalyst on the yield of benzodioxoles were investigated. Results show that HY is an efficient catalyst for the acetalization and ketalization with high conversion and selectivity in mild conditions. The best reaction conditions: molar ratio of catechol to aldehydes or ketones is 1:1.4, catalyst amount is 3.5 g/l mol catechol, reaction time is 5 h. Under these conditions, the conversion and selectivity were over 50\% and 97\%, respectively.",

keywords = "Benzodioxoles, Catalyze, Condensation, HY zeolite, Synthesis",

author = "Xuezheng Liang and Shan Gao and Jianguo Yang and Caihua Liu and Xinyu Yu and Mingyuan He",

year = "2007",

month = mar,

doi = "10.1007/s11458-007-0007-7",

language = "英语",

volume = "2",

pages = "31--34",

journal = "Frontiers of Chemistry in China",

issn = "1673-3495",

publisher = "Higher Education Press Limited Company",

number = "1",

}

TY - JOUR

T1 - Study on catalytic synthesis of 1,3-benzodioxoles by HY zeolite

AU - Liang, Xuezheng

AU - Gao, Shan

AU - Yang, Jianguo

AU - Liu, Caihua

AU - Yu, Xinyu

AU - He, Mingyuan

PY - 2007/3

Y1 - 2007/3

N2 - The acetalization and ketalization of various aldehydes and ketones with catechol by using HY zeolite as catalyst were studied. Effect of the reaction time, mole ratio of reactants, and amount of catalyst on the yield of benzodioxoles were investigated. Results show that HY is an efficient catalyst for the acetalization and ketalization with high conversion and selectivity in mild conditions. The best reaction conditions: molar ratio of catechol to aldehydes or ketones is 1:1.4, catalyst amount is 3.5 g/l mol catechol, reaction time is 5 h. Under these conditions, the conversion and selectivity were over 50% and 97%, respectively.

AB - The acetalization and ketalization of various aldehydes and ketones with catechol by using HY zeolite as catalyst were studied. Effect of the reaction time, mole ratio of reactants, and amount of catalyst on the yield of benzodioxoles were investigated. Results show that HY is an efficient catalyst for the acetalization and ketalization with high conversion and selectivity in mild conditions. The best reaction conditions: molar ratio of catechol to aldehydes or ketones is 1:1.4, catalyst amount is 3.5 g/l mol catechol, reaction time is 5 h. Under these conditions, the conversion and selectivity were over 50% and 97%, respectively.

KW - Benzodioxoles

KW - Catalyze

KW - Condensation

KW - HY zeolite

KW - Synthesis

UR - https://www.scopus.com/pages/publications/33847715080

U2 - 10.1007/s11458-007-0007-7

DO - 10.1007/s11458-007-0007-7

M3 - 文章

AN - SCOPUS:33847715080

SN - 1673-3495

VL - 2

SP - 31

EP - 34

JO - Frontiers of Chemistry in China

JF - Frontiers of Chemistry in China

IS - 1

ER -

Study on catalytic synthesis of 1,3-benzodioxoles by HY zeolite

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this