Study on catalytic synthesis of 1,3-benzodioxoles by HAIMCM-41 zeolite

Xue Zheng Liang; Shan Gao; Cai Hua Liu; Xin Yu Yu; Jian Guo Yang; Ming Yuan He

Study on catalytic synthesis of 1,3-benzodioxoles by HAIMCM-41 zeolite

Xue Zheng Liang, Shan Gao, Cai Hua Liu, Xin Yu Yu, Jian Guo Yang, Ming Yuan He

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

The acetalization and ketalization of various aldehydes and ketones with catechol using HA1MCM-41 zeolite as catalyst were studied. Results showed that HA1MCM-41 was an efficient catalyst for the acetalization and ketalization with high conversion and selectivity in mild conditions. The best reaction condition is that molar ratio of catechol to aldehydes or ketones was 1 : 1.4, catalyst amount was 3.5 g/mol catechol, reaction time was 4 h, n(SiO₂)/ n(Al₂O₃) = 15. Under this condition, conversion was over 85.6% and selectivity was over 99.4%.

Original language	English
Pages (from-to)	970-975
Number of pages	6
Journal	Chinese Journal of Organic Chemistry
Volume	27
Issue number	8
State	Published - Aug 2007

Keywords

Benzodioxole
Catalyze
Condensation
Synthesis
Zeolite

Cite this

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title = "Study on catalytic synthesis of 1,3-benzodioxoles by HAIMCM-41 zeolite",

abstract = "The acetalization and ketalization of various aldehydes and ketones with catechol using HA1MCM-41 zeolite as catalyst were studied. Results showed that HA1MCM-41 was an efficient catalyst for the acetalization and ketalization with high conversion and selectivity in mild conditions. The best reaction condition is that molar ratio of catechol to aldehydes or ketones was 1 : 1.4, catalyst amount was 3.5 g/mol catechol, reaction time was 4 h, n(SiO2)/ n(Al2O3) = 15. Under this condition, conversion was over 85.6\% and selectivity was over 99.4\%.",

keywords = "Benzodioxole, Catalyze, Condensation, Synthesis, Zeolite",

author = "Liang, \{Xue Zheng\} and Shan Gao and Liu, \{Cai Hua\} and Yu, \{Xin Yu\} and Yang, \{Jian Guo\} and He, \{Ming Yuan\}",

year = "2007",

month = aug,

language = "英语",

volume = "27",

pages = "970--975",

journal = "Chinese Journal of Organic Chemistry",

issn = "0253-2786",

publisher = "Science Press ",

number = "8",

}

TY - JOUR

T1 - Study on catalytic synthesis of 1,3-benzodioxoles by HAIMCM-41 zeolite

AU - Liang, Xue Zheng

AU - Gao, Shan

AU - Liu, Cai Hua

AU - Yu, Xin Yu

AU - Yang, Jian Guo

AU - He, Ming Yuan

PY - 2007/8

Y1 - 2007/8

N2 - The acetalization and ketalization of various aldehydes and ketones with catechol using HA1MCM-41 zeolite as catalyst were studied. Results showed that HA1MCM-41 was an efficient catalyst for the acetalization and ketalization with high conversion and selectivity in mild conditions. The best reaction condition is that molar ratio of catechol to aldehydes or ketones was 1 : 1.4, catalyst amount was 3.5 g/mol catechol, reaction time was 4 h, n(SiO2)/ n(Al2O3) = 15. Under this condition, conversion was over 85.6% and selectivity was over 99.4%.

AB - The acetalization and ketalization of various aldehydes and ketones with catechol using HA1MCM-41 zeolite as catalyst were studied. Results showed that HA1MCM-41 was an efficient catalyst for the acetalization and ketalization with high conversion and selectivity in mild conditions. The best reaction condition is that molar ratio of catechol to aldehydes or ketones was 1 : 1.4, catalyst amount was 3.5 g/mol catechol, reaction time was 4 h, n(SiO2)/ n(Al2O3) = 15. Under this condition, conversion was over 85.6% and selectivity was over 99.4%.

KW - Benzodioxole

KW - Catalyze

KW - Condensation

KW - Synthesis

KW - Zeolite

UR - https://www.scopus.com/pages/publications/35248848851

M3 - 文章

AN - SCOPUS:35248848851

SN - 0253-2786

VL - 27

SP - 970

EP - 975

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 8

ER -

Study on catalytic synthesis of 1,3-benzodioxoles by HAIMCM-41 zeolite

Abstract

Keywords

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