Studies on the synthesis of morphinan alkaloid: Preparation of the key allylic silyl ether precursor

Zhen Lei Song; Yong Qiang Tu; Shuan Hu Gao; Yi Jun Jiang; Shu Yu Zhang

Studies on the synthesis of morphinan alkaloid: Preparation of the key allylic silyl ether precursor

Zhen Lei Song^*
, Yong Qiang Tu
, Shuan Hu Gao
, Yi Jun Jiang
, Shu Yu Zhang

^*Corresponding author for this work

Lanzhou University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A convergent strategy to the key allylic silyl ether precursor 4 in our synthetic efforts toward morphinan alkaloid is presented. The vital step is the selective 1,2-addition of the organocerium agent of 6 to ketene 5.

Original language	English
Pages (from-to)	1445-1447
Number of pages	3
Journal	Chinese Chemical Letters
Volume	16
Issue number	11
State	Published - Nov 2005
Externally published	Yes

Keywords

Cerium chloride
Morphinan alkaloid
Synthesis
Weinreb amide

Cite this

@article{62e4355c534a484a9758e2da3f5c809c,

title = "Studies on the synthesis of morphinan alkaloid: Preparation of the key allylic silyl ether precursor",

abstract = "A convergent strategy to the key allylic silyl ether precursor 4 in our synthetic efforts toward morphinan alkaloid is presented. The vital step is the selective 1,2-addition of the organocerium agent of 6 to ketene 5.",

keywords = "Cerium chloride, Morphinan alkaloid, Synthesis, Weinreb amide",

author = "Song, \{Zhen Lei\} and Tu, \{Yong Qiang\} and Gao, \{Shuan Hu\} and Jiang, \{Yi Jun\} and Zhang, \{Shu Yu\}",

year = "2005",

month = nov,

language = "英语",

volume = "16",

pages = "1445--1447",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "11",

}

TY - JOUR

T1 - Studies on the synthesis of morphinan alkaloid

T2 - Preparation of the key allylic silyl ether precursor

AU - Song, Zhen Lei

AU - Tu, Yong Qiang

AU - Gao, Shuan Hu

AU - Jiang, Yi Jun

AU - Zhang, Shu Yu

PY - 2005/11

Y1 - 2005/11

N2 - A convergent strategy to the key allylic silyl ether precursor 4 in our synthetic efforts toward morphinan alkaloid is presented. The vital step is the selective 1,2-addition of the organocerium agent of 6 to ketene 5.

AB - A convergent strategy to the key allylic silyl ether precursor 4 in our synthetic efforts toward morphinan alkaloid is presented. The vital step is the selective 1,2-addition of the organocerium agent of 6 to ketene 5.

KW - Cerium chloride

KW - Morphinan alkaloid

KW - Synthesis

KW - Weinreb amide

UR - https://www.scopus.com/pages/publications/33745056917

M3 - 文章

AN - SCOPUS:33745056917

SN - 1001-8417

VL - 16

SP - 1445

EP - 1447

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 11

ER -

Studies on the synthesis of morphinan alkaloid: Preparation of the key allylic silyl ether precursor

Abstract

Keywords

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