Structure elucidation of the highly active titanosilicate catalyst Ti-YNU-1

Juanfang Ruan; Peng Wu; Ben Slater; Osamu Terasaki

doi:10.1002/anie.200501939

Structure elucidation of the highly active titanosilicate catalyst Ti-YNU-1

Juanfang Ruan^*
, Peng Wu
, Ben Slater
, Osamu Terasaki

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

Between the sheets: The structure of the titanosilicate Ti-YNU-1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti-MWW (see picture). Formation of twelve-membered rings would explain this cell expansion, which results in increased steric accessibility and may explain the higher catalytic activity of Ti-YNU-1 relative to other titanosilicates. (Chemical Equation Presented).

Original language	English
Pages (from-to)	6719-6723
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	41
DOIs	https://doi.org/10.1002/anie.200501939
State	Published - 21 Oct 2005

Keywords

Layered compounds
Silicates
Structure elucidation
Titanates
Zeolite analogues

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10.1002/anie.200501939

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abstract = "Between the sheets: The structure of the titanosilicate Ti-YNU-1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti-MWW (see picture). Formation of twelve-membered rings would explain this cell expansion, which results in increased steric accessibility and may explain the higher catalytic activity of Ti-YNU-1 relative to other titanosilicates. (Chemical Equation Presented).",

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author = "Juanfang Ruan and Peng Wu and Ben Slater and Osamu Terasaki",

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AU - Ruan, Juanfang

AU - Wu, Peng

AU - Slater, Ben

AU - Terasaki, Osamu

PY - 2005/10/21

Y1 - 2005/10/21

N2 - Between the sheets: The structure of the titanosilicate Ti-YNU-1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti-MWW (see picture). Formation of twelve-membered rings would explain this cell expansion, which results in increased steric accessibility and may explain the higher catalytic activity of Ti-YNU-1 relative to other titanosilicates. (Chemical Equation Presented).

AB - Between the sheets: The structure of the titanosilicate Ti-YNU-1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti-MWW (see picture). Formation of twelve-membered rings would explain this cell expansion, which results in increased steric accessibility and may explain the higher catalytic activity of Ti-YNU-1 relative to other titanosilicates. (Chemical Equation Presented).

KW - Layered compounds

KW - Silicates

KW - Structure elucidation

KW - Titanates

KW - Zeolite analogues

UR - https://www.scopus.com/pages/publications/27444445833

U2 - 10.1002/anie.200501939

DO - 10.1002/anie.200501939

M3 - 文章

AN - SCOPUS:27444445833

SN - 1433-7851

VL - 44

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 41

ER -

Structure elucidation of the highly active titanosilicate catalyst Ti-YNU-1

Abstract

Keywords

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