Structural characterization of copper-phthalocyanine thin solid films by FTIR spectroscopy

Hanming Ding; Yin Zhang; Wenqi Chen; Shiquan Xi

Structural characterization of copper-phthalocyanine thin solid films by FTIR spectroscopy

Hanming Ding, Yin Zhang, Wenqi Chen, Shiquan Xi

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of tris- (2, 4-di-t-amylpheoxy) - (8-quinolinoxy) copper phthalocyanine (CuPc) thin solid films has been characterized by Fourier transform infrared (FTIR) transmission, polarized transmission and reflection absorption (RA) spectroscopy. The following conclusions can be obtained from the above measurements: (1) in LB films, the hydrocarbon chains of CuPc are in hexagonal or pseudohexagonal subcell packing, the CH ₂ asymmetric vibrational vector is oriented with respect to the substrate surface and the RA spectroscopy can distinguish the two CH ₂ streching modes of benzene cycle; (2) in sublimed films, the molecules of CuPc are out of order.

Original language	English
Pages (from-to)	76
Number of pages	1
Journal	Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
Volume	17
Issue number	2
State	Published - 1997
Externally published	Yes

Keywords

Copper phthalocyanine
FTIR spectroscopy
Langmuir-Blodgett film
Sublimed film

Cite this

@article{cb29e5a3385f4209bedd0d159dd30165,

title = "Structural characterization of copper-phthalocyanine thin solid films by FTIR spectroscopy",

abstract = "The structure of tris- (2, 4-di-t-amylpheoxy) - (8-quinolinoxy) copper phthalocyanine (CuPc) thin solid films has been characterized by Fourier transform infrared (FTIR) transmission, polarized transmission and reflection absorption (RA) spectroscopy. The following conclusions can be obtained from the above measurements: (1) in LB films, the hydrocarbon chains of CuPc are in hexagonal or pseudohexagonal subcell packing, the CH 2 asymmetric vibrational vector is oriented with respect to the substrate surface and the RA spectroscopy can distinguish the two CH 2 streching modes of benzene cycle; (2) in sublimed films, the molecules of CuPc are out of order.",

keywords = "Copper phthalocyanine, FTIR spectroscopy, Langmuir-Blodgett film, Sublimed film",

author = "Hanming Ding and Yin Zhang and Wenqi Chen and Shiquan Xi",

year = "1997",

language = "英语",

volume = "17",

pages = "76",

journal = "Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis",

issn = "1000-0593",

publisher = "Science Press ",

number = "2",

}

TY - JOUR

T1 - Structural characterization of copper-phthalocyanine thin solid films by FTIR spectroscopy

AU - Ding, Hanming

AU - Zhang, Yin

AU - Chen, Wenqi

AU - Xi, Shiquan

PY - 1997

Y1 - 1997

N2 - The structure of tris- (2, 4-di-t-amylpheoxy) - (8-quinolinoxy) copper phthalocyanine (CuPc) thin solid films has been characterized by Fourier transform infrared (FTIR) transmission, polarized transmission and reflection absorption (RA) spectroscopy. The following conclusions can be obtained from the above measurements: (1) in LB films, the hydrocarbon chains of CuPc are in hexagonal or pseudohexagonal subcell packing, the CH 2 asymmetric vibrational vector is oriented with respect to the substrate surface and the RA spectroscopy can distinguish the two CH 2 streching modes of benzene cycle; (2) in sublimed films, the molecules of CuPc are out of order.

AB - The structure of tris- (2, 4-di-t-amylpheoxy) - (8-quinolinoxy) copper phthalocyanine (CuPc) thin solid films has been characterized by Fourier transform infrared (FTIR) transmission, polarized transmission and reflection absorption (RA) spectroscopy. The following conclusions can be obtained from the above measurements: (1) in LB films, the hydrocarbon chains of CuPc are in hexagonal or pseudohexagonal subcell packing, the CH 2 asymmetric vibrational vector is oriented with respect to the substrate surface and the RA spectroscopy can distinguish the two CH 2 streching modes of benzene cycle; (2) in sublimed films, the molecules of CuPc are out of order.

KW - Copper phthalocyanine

KW - FTIR spectroscopy

KW - Langmuir-Blodgett film

KW - Sublimed film

UR - https://www.scopus.com/pages/publications/3643107771

M3 - 文章

AN - SCOPUS:3643107771

SN - 1000-0593

VL - 17

SP - 76

JO - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

JF - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

IS - 2

ER -

Structural characterization of copper-phthalocyanine thin solid films by FTIR spectroscopy

Abstract

Keywords

Other files and links

Fingerprint

Cite this