Abstract
In this work we studied 90 nm thick copolymer thin films of vinylidene fluoride (70%) with trifluoroethylene (30%) grown by Langmuir-Blodgett onto silicon substrates. The effects of two different bottom electrodes, namely, Al and LaNiO3 (LNO) are investigated. A Debye-like relaxation near 320 K is enlarged by LNO bottom electrode. X-ray diffraction pattern attests that two different crystallographic structures coexist below 340 K in film deposited on LNO. Compared with Al electrode, LNO electrode strongly increases defects or gauche segments in film and further weakens properties of film.
| Original language | English |
|---|---|
| Article number | 054111 |
| Journal | Journal of Applied Physics |
| Volume | 106 |
| Issue number | 5 |
| DOIs | |
| State | Published - 2009 |
| Externally published | Yes |