Stereoselective total synthesis of (3R,8S)-falcarindiol, a common polyacetylenic compound from umbellifers

Guangrong Zheng; Wei Lu; Junchao Cai

doi:10.1021/np980418z

Stereoselective total synthesis of (3R,8S)-falcarindiol, a common polyacetylenic compound from umbellifers

Guangrong Zheng
, Wei Lu
, Junchao Cai^*

^*Corresponding author for this work

CAS - Shanghai Institute of Materia Medica

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

The first stereoselective total synthesis of (3R,8S)-falcarindiol (1) from L-tartaric acid and D-xylose is reported, via the Cadiot-Chodkiczwicz reaction, to couple 1-bromoalkyne (2) with 3(R)-(tert-butyldiphenylsilyloxy)- 1-penten-4-yne (3).

Original language	English
Pages (from-to)	626-628
Number of pages	3
Journal	Journal of Natural Products
Volume	62
Issue number	4
DOIs	https://doi.org/10.1021/np980418z
State	Published - Apr 1999
Externally published	Yes

Access to Document

10.1021/np980418z

Cite this

@article{af8c317fed02464db7492c6f5fee3830,

title = "Stereoselective total synthesis of (3R,8S)-falcarindiol, a common polyacetylenic compound from umbellifers",

abstract = "The first stereoselective total synthesis of (3R,8S)-falcarindiol (1) from L-tartaric acid and D-xylose is reported, via the Cadiot-Chodkiczwicz reaction, to couple 1-bromoalkyne (2) with 3(R)-(tert-butyldiphenylsilyloxy)- 1-penten-4-yne (3).",

author = "Guangrong Zheng and Wei Lu and Junchao Cai",

year = "1999",

month = apr,

doi = "10.1021/np980418z",

language = "英语",

volume = "62",

pages = "626--628",

journal = "Journal of Natural Products",

issn = "0163-3864",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Stereoselective total synthesis of (3R,8S)-falcarindiol, a common polyacetylenic compound from umbellifers

AU - Zheng, Guangrong

AU - Lu, Wei

AU - Cai, Junchao

PY - 1999/4

Y1 - 1999/4

N2 - The first stereoselective total synthesis of (3R,8S)-falcarindiol (1) from L-tartaric acid and D-xylose is reported, via the Cadiot-Chodkiczwicz reaction, to couple 1-bromoalkyne (2) with 3(R)-(tert-butyldiphenylsilyloxy)- 1-penten-4-yne (3).

AB - The first stereoselective total synthesis of (3R,8S)-falcarindiol (1) from L-tartaric acid and D-xylose is reported, via the Cadiot-Chodkiczwicz reaction, to couple 1-bromoalkyne (2) with 3(R)-(tert-butyldiphenylsilyloxy)- 1-penten-4-yne (3).

UR - https://www.scopus.com/pages/publications/0032901889

U2 - 10.1021/np980418z

DO - 10.1021/np980418z

M3 - 文章

AN - SCOPUS:0032901889

SN - 0163-3864

VL - 62

SP - 626

EP - 628

JO - Journal of Natural Products

JF - Journal of Natural Products

IS - 4

ER -

Stereoselective total synthesis of (3R,8S)-falcarindiol, a common polyacetylenic compound from umbellifers

Abstract

Access to Document

Other files and links

Fingerprint

Cite this