Stereoselective synthesis of 1,3,5-trienes from alkynones and allyl carbonyl compounds through C-C σ-bond cleavage under transition-metal-free conditions

Lu Cheng; Mengdan Wang; Yajie Yang; Zongkang Wang; Yilin Zhu; Lingkai Kong; Yanzhong Li

doi:10.1039/d2qo00617k

Stereoselective synthesis of 1,3,5-trienes from alkynones and allyl carbonyl compounds through C-C σ-bond cleavage under transition-metal-free conditions

Lu Cheng
, Mengdan Wang
, Yajie Yang
, Zongkang Wang
, Yilin Zhu
, Lingkai Kong^*
, Yanzhong Li^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
Linyi University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

An atom-economical transition-metal-free protocol for the stereoselective synthesis of conjugated trienes has been developed. These transformations were realized through base promoted C-C σ-bond cleavage reactions of allyl carbonyl compounds. This methodology efficiently constructs a broad range of conjugated trienes with the advantages of mild reaction conditions, low cost and operational simplicity.

Original language	English
Pages (from-to)	3354-3359
Number of pages	6
Journal	Organic Chemistry Frontiers
Volume	9
Issue number	12
DOIs	https://doi.org/10.1039/d2qo00617k
State	Published - 5 May 2022

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title = "Stereoselective synthesis of 1,3,5-trienes from alkynones and allyl carbonyl compounds through C-C σ-bond cleavage under transition-metal-free conditions",

abstract = "An atom-economical transition-metal-free protocol for the stereoselective synthesis of conjugated trienes has been developed. These transformations were realized through base promoted C-C σ-bond cleavage reactions of allyl carbonyl compounds. This methodology efficiently constructs a broad range of conjugated trienes with the advantages of mild reaction conditions, low cost and operational simplicity.",

author = "Lu Cheng and Mengdan Wang and Yajie Yang and Zongkang Wang and Yilin Zhu and Lingkai Kong and Yanzhong Li",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",

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T1 - Stereoselective synthesis of 1,3,5-trienes from alkynones and allyl carbonyl compounds through C-C σ-bond cleavage under transition-metal-free conditions

AU - Cheng, Lu

AU - Wang, Mengdan

AU - Yang, Yajie

AU - Wang, Zongkang

AU - Zhu, Yilin

AU - Kong, Lingkai

AU - Li, Yanzhong

PY - 2022/5/5

Y1 - 2022/5/5

N2 - An atom-economical transition-metal-free protocol for the stereoselective synthesis of conjugated trienes has been developed. These transformations were realized through base promoted C-C σ-bond cleavage reactions of allyl carbonyl compounds. This methodology efficiently constructs a broad range of conjugated trienes with the advantages of mild reaction conditions, low cost and operational simplicity.

AB - An atom-economical transition-metal-free protocol for the stereoselective synthesis of conjugated trienes has been developed. These transformations were realized through base promoted C-C σ-bond cleavage reactions of allyl carbonyl compounds. This methodology efficiently constructs a broad range of conjugated trienes with the advantages of mild reaction conditions, low cost and operational simplicity.

UR - https://www.scopus.com/pages/publications/85133701253

U2 - 10.1039/d2qo00617k

DO - 10.1039/d2qo00617k

M3 - 文章

AN - SCOPUS:85133701253

SN - 2052-4110

VL - 9

SP - 3354

EP - 3359

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 12

ER -

Stereoselective synthesis of 1,3,5-trienes from alkynones and allyl carbonyl compounds through C-C σ-bond cleavage under transition-metal-free conditions

Abstract

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