Steam-stable zeolitic imidazolate framework ZIF-90 membrane with hydrogen selectivity through covalent functionalization

Aisheng Huang; Wei Dou; Jürgen Caro

doi:10.1021/ja108774v

Steam-stable zeolitic imidazolate framework ZIF-90 membrane with hydrogen selectivity through covalent functionalization

Aisheng Huang^*
, Wei Dou
, Jürgen Caro

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

537 Scopus citations

Abstract

A novel covalent functionalization strategy was developed to prepare reproducible ZIF-90 molecular sieve membranes by using 3- aminopropyltriethoxysilane as a covalent linker between the ZIF-90 layer and Al₂O₃ support via imines condensation. The ZIF-90 membranes show high thermal and hydrothermal stabilities, and they allow the separation of hydrogen from larger gases by molecular sieving.

Original language	English
Pages (from-to)	15562-15564
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	132
Issue number	44
DOIs	https://doi.org/10.1021/ja108774v
State	Published - 10 Nov 2010
Externally published	Yes

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10.1021/ja108774v

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title = "Steam-stable zeolitic imidazolate framework ZIF-90 membrane with hydrogen selectivity through covalent functionalization",

abstract = "A novel covalent functionalization strategy was developed to prepare reproducible ZIF-90 molecular sieve membranes by using 3- aminopropyltriethoxysilane as a covalent linker between the ZIF-90 layer and Al2O3 support via imines condensation. The ZIF-90 membranes show high thermal and hydrothermal stabilities, and they allow the separation of hydrogen from larger gases by molecular sieving.",

author = "Aisheng Huang and Wei Dou and J{\"u}rgen Caro",

year = "2010",

month = nov,

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doi = "10.1021/ja108774v",

language = "英语",

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AU - Huang, Aisheng

AU - Dou, Wei

AU - Caro, Jürgen

PY - 2010/11/10

Y1 - 2010/11/10

N2 - A novel covalent functionalization strategy was developed to prepare reproducible ZIF-90 molecular sieve membranes by using 3- aminopropyltriethoxysilane as a covalent linker between the ZIF-90 layer and Al2O3 support via imines condensation. The ZIF-90 membranes show high thermal and hydrothermal stabilities, and they allow the separation of hydrogen from larger gases by molecular sieving.

AB - A novel covalent functionalization strategy was developed to prepare reproducible ZIF-90 molecular sieve membranes by using 3- aminopropyltriethoxysilane as a covalent linker between the ZIF-90 layer and Al2O3 support via imines condensation. The ZIF-90 membranes show high thermal and hydrothermal stabilities, and they allow the separation of hydrogen from larger gases by molecular sieving.

UR - https://www.scopus.com/pages/publications/78149270288

U2 - 10.1021/ja108774v

DO - 10.1021/ja108774v

M3 - 文章

AN - SCOPUS:78149270288

SN - 0002-7863

VL - 132

SP - 15562

EP - 15564

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 44

ER -

Steam-stable zeolitic imidazolate framework ZIF-90 membrane with hydrogen selectivity through covalent functionalization

Abstract

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