Sorption and desorption characteristics of Eu(III) on red earth

The batch method and the column method were simultaneously employed to study the sorption and desorption of Eu(III) on red earth as a function of pH (4.6-6), the presence of a well-characterized fulvic acid (FA) and the iron oxides content of red earth. The results from both methods were consistent qualitatively. The Eu(III) sorption showed significant dependencies on pH and FA, the sorption was increased with increasing pH and by addition of FA to the solutions, while the iron oxides content of the red earth had a negative contribution to the sorption of Eu(III). Additionally, the sorption- desorption hysteresis of Eu(III) on red earth occurred at a pH range of 4.6- 6. Therefore, the humic substance and high pH have a great tendency to immobilize Eu(llI) on red earth.