Solution-processable n-type and ambipolar semiconductors based on a fused cyclopentadithiophenebis(dicyanovinylene) core

Xueliang Shi; Jingjing Chang; Chunyan Chi

doi:10.1039/c3cc43680b

Solution-processable n-type and ambipolar semiconductors based on a fused cyclopentadithiophenebis(dicyanovinylene) core

Xueliang Shi
, Jingjing Chang
, Chunyan Chi^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Two fused cyclopentadithiophenebis(dicyanovinylene) derivatives (FCPDT-16 andFCPDT-C24) with a low-lying LUMO energy level (-3.88 eV) and a rigid core structure were successfully synthesized. They have good thermal stability and form highly ordered packing structures both in the bulk solid state and in thin films. The field effect transistors fabricated from a solution of these two compounds showed ambipolar behaviour with major n-channel operation.FCPDT-C16 exhibited electron mobility up to 0.16 cm² V^-1 s^-1.

Original language	English
Pages (from-to)	7135-7137
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	64
DOIs	https://doi.org/10.1039/c3cc43680b
State	Published - 16 Jul 2013
Externally published	Yes

Access to Document

10.1039/c3cc43680b

Cite this

@article{b9243b4414954c4f8dacc955d491a54c,

title = "Solution-processable n-type and ambipolar semiconductors based on a fused cyclopentadithiophenebis(dicyanovinylene) core",

abstract = "Two fused cyclopentadithiophenebis(dicyanovinylene) derivatives (FCPDT-16 andFCPDT-C24) with a low-lying LUMO energy level (-3.88 eV) and a rigid core structure were successfully synthesized. They have good thermal stability and form highly ordered packing structures both in the bulk solid state and in thin films. The field effect transistors fabricated from a solution of these two compounds showed ambipolar behaviour with major n-channel operation.FCPDT-C16 exhibited electron mobility up to 0.16 cm2 V-1 s-1.",

author = "Xueliang Shi and Jingjing Chang and Chunyan Chi",

year = "2013",

month = jul,

day = "16",

doi = "10.1039/c3cc43680b",

language = "英语",

volume = "49",

pages = "7135--7137",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "64",

}

TY - JOUR

T1 - Solution-processable n-type and ambipolar semiconductors based on a fused cyclopentadithiophenebis(dicyanovinylene) core

AU - Shi, Xueliang

AU - Chang, Jingjing

AU - Chi, Chunyan

PY - 2013/7/16

Y1 - 2013/7/16

N2 - Two fused cyclopentadithiophenebis(dicyanovinylene) derivatives (FCPDT-16 andFCPDT-C24) with a low-lying LUMO energy level (-3.88 eV) and a rigid core structure were successfully synthesized. They have good thermal stability and form highly ordered packing structures both in the bulk solid state and in thin films. The field effect transistors fabricated from a solution of these two compounds showed ambipolar behaviour with major n-channel operation.FCPDT-C16 exhibited electron mobility up to 0.16 cm2 V-1 s-1.

AB - Two fused cyclopentadithiophenebis(dicyanovinylene) derivatives (FCPDT-16 andFCPDT-C24) with a low-lying LUMO energy level (-3.88 eV) and a rigid core structure were successfully synthesized. They have good thermal stability and form highly ordered packing structures both in the bulk solid state and in thin films. The field effect transistors fabricated from a solution of these two compounds showed ambipolar behaviour with major n-channel operation.FCPDT-C16 exhibited electron mobility up to 0.16 cm2 V-1 s-1.

UR - https://www.scopus.com/pages/publications/84880341923

U2 - 10.1039/c3cc43680b

DO - 10.1039/c3cc43680b

M3 - 文章

AN - SCOPUS:84880341923

SN - 1359-7345

VL - 49

SP - 7135

EP - 7137

JO - Chemical Communications

JF - Chemical Communications

IS - 64

ER -

Solution-processable n-type and ambipolar semiconductors based on a fused cyclopentadithiophenebis(dicyanovinylene) core

Abstract

Access to Document

Other files and links

Fingerprint

Cite this