Solution grafting of Ti(IV) inside MCM-41 materials

W. H. Zhang; J. L. Shi; H. R. Chen; J. N. Yan; Z. L. Hua; D. S. Yan

Solution grafting of Ti(IV) inside MCM-41 materials

W. H. Zhang, J. L. Shi, H. R. Chen, J. N. Yan, Z. L. Hua, D. S. Yan

CAS - Shanghai Institute of Ceramics

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Ti(IV) was grafted onto the frameworks of MCM-41 material by solution grafting reaction scheme. The product was extensively characterized by XRD, TEM, EDS, and N₂ adsorption-desorption isotherms as well as FTIR and ²⁹Si MAS NMR methods. Three mechanisms of the solution grafting reaction were put forward. Experimental results show that the Si-OH groups react with Ti(OBu)₄ and form Si-O-Ti bands, which are marked by the strong absorption at 950-960 cm^-1 in IR spectra.

Original language	English
Pages (from-to)	87-92
Number of pages	6
Journal	Wuji Cailiao Xuebao/Journal of Inorganic Materials
Volume	16
Issue number	1
State	Published - Jan 2001
Externally published	Yes

Keywords

Mesoporous materials
Solution grafting

Cite this

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title = "Solution grafting of Ti(IV) inside MCM-41 materials",

abstract = "Ti(IV) was grafted onto the frameworks of MCM-41 material by solution grafting reaction scheme. The product was extensively characterized by XRD, TEM, EDS, and N2 adsorption-desorption isotherms as well as FTIR and 29Si MAS NMR methods. Three mechanisms of the solution grafting reaction were put forward. Experimental results show that the Si-OH groups react with Ti(OBu)4 and form Si-O-Ti bands, which are marked by the strong absorption at 950-960 cm-1 in IR spectra.",

keywords = "Mesoporous materials, Solution grafting",

author = "Zhang, \{W. H.\} and Shi, \{J. L.\} and Chen, \{H. R.\} and Yan, \{J. N.\} and Hua, \{Z. L.\} and Yan, \{D. S.\}",

year = "2001",

month = jan,

language = "英语",

volume = "16",

pages = "87--92",

journal = "Wuji Cailiao Xuebao/Journal of Inorganic Materials",

issn = "1000-324X",

publisher = "Science Press ",

number = "1",

}

TY - JOUR

T1 - Solution grafting of Ti(IV) inside MCM-41 materials

AU - Zhang, W. H.

AU - Shi, J. L.

AU - Chen, H. R.

AU - Yan, J. N.

AU - Hua, Z. L.

AU - Yan, D. S.

PY - 2001/1

Y1 - 2001/1

N2 - Ti(IV) was grafted onto the frameworks of MCM-41 material by solution grafting reaction scheme. The product was extensively characterized by XRD, TEM, EDS, and N2 adsorption-desorption isotherms as well as FTIR and 29Si MAS NMR methods. Three mechanisms of the solution grafting reaction were put forward. Experimental results show that the Si-OH groups react with Ti(OBu)4 and form Si-O-Ti bands, which are marked by the strong absorption at 950-960 cm-1 in IR spectra.

AB - Ti(IV) was grafted onto the frameworks of MCM-41 material by solution grafting reaction scheme. The product was extensively characterized by XRD, TEM, EDS, and N2 adsorption-desorption isotherms as well as FTIR and 29Si MAS NMR methods. Three mechanisms of the solution grafting reaction were put forward. Experimental results show that the Si-OH groups react with Ti(OBu)4 and form Si-O-Ti bands, which are marked by the strong absorption at 950-960 cm-1 in IR spectra.

KW - Mesoporous materials

KW - Solution grafting

UR - https://www.scopus.com/pages/publications/0034864458

M3 - 文章

AN - SCOPUS:0034864458

SN - 1000-324X

VL - 16

SP - 87

EP - 92

JO - Wuji Cailiao Xuebao/Journal of Inorganic Materials

JF - Wuji Cailiao Xuebao/Journal of Inorganic Materials

IS - 1

ER -

Solution grafting of Ti(IV) inside MCM-41 materials

Abstract

Keywords

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