Single-calcination synthesis of pyrochlore-free Pb(Ni1/3Nb 2/3)O3-PbTiO3 using a coating method

Ping Hua Xiang; Ni Zhong; Xian Lin Dong

doi:10.1016/S0038-1098(03)00630-6

Single-calcination synthesis of pyrochlore-free Pb(Ni_1/3Nb _2/3)O₃-PbTiO₃ using a coating method

Ping Hua Xiang, Ni Zhong, Xian Lin Dong

CAS - Shanghai Institute of Ceramics

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Pyrochlore-free 0.64Pb(Ni_1/3Nb_2/3)O ₃-0.36PbTiO₃ (0.64PNN-0.36PT) powder has been successfully synthesized by only one calcination step using a coating method. The formation of pyrochlore phase is prevented by coating NiCO ₃·2Ni(OH)₂·2H₂O on Nb ₂O₅ particles. NiCO₃·2Ni(OH) ₂·2H₂O-coated Nb₂O₅ powder is prepared by heterogeneous precipitation method. The coating structure is confirmed by transmission electron microscope (TEM) with energy dispersive spectroscope (EDS). Single calcination treatment of the coating powder mixed with appropriate amounts of Pb₃O₄ and TiO₂ powders at 900 °C for 2 h produces the pure-perovskite 0.64PNN-0.36PT powder. The elimination of the pyrochlore phase can be explained in terms of the separating of Pb₃O₄ and Nb₂O₅ by the NiCO₃·2Ni(OH)₂·2H₂O coating layer.

Original language	English
Pages (from-to)	699-701
Number of pages	3
Journal	Solid State Communications
Volume	127
Issue number	11
DOIs	https://doi.org/10.1016/S0038-1098(03)00630-6
State	Published - Sep 2003
Externally published	Yes

Keywords

A. Ferroelectrics
A. Lead nickel niobate
B. Coating method
C. Morphotropic phase boundary

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10.1016/S0038-1098(03)00630-6

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@article{cd4e7913baff474b91d25add7231f500,

title = "Single-calcination synthesis of pyrochlore-free Pb(Ni1/3Nb 2/3)O3-PbTiO3 using a coating method",

abstract = "Pyrochlore-free 0.64Pb(Ni1/3Nb2/3)O 3-0.36PbTiO3 (0.64PNN-0.36PT) powder has been successfully synthesized by only one calcination step using a coating method. The formation of pyrochlore phase is prevented by coating NiCO 3·2Ni(OH)2·2H2O on Nb 2O5 particles. NiCO3·2Ni(OH) 2·2H2O-coated Nb2O5 powder is prepared by heterogeneous precipitation method. The coating structure is confirmed by transmission electron microscope (TEM) with energy dispersive spectroscope (EDS). Single calcination treatment of the coating powder mixed with appropriate amounts of Pb3O4 and TiO2 powders at 900 °C for 2 h produces the pure-perovskite 0.64PNN-0.36PT powder. The elimination of the pyrochlore phase can be explained in terms of the separating of Pb3O4 and Nb2O5 by the NiCO3·2Ni(OH)2·2H2O coating layer.",

keywords = "A. Ferroelectrics, A. Lead nickel niobate, B. Coating method, C. Morphotropic phase boundary",

author = "Xiang, \{Ping Hua\} and Ni Zhong and Dong, \{Xian Lin\}",

year = "2003",

month = sep,

doi = "10.1016/S0038-1098(03)00630-6",

language = "英语",

volume = "127",

pages = "699--701",

journal = "Solid State Communications",

issn = "0038-1098",

publisher = "Elsevier Ltd",

number = "11",

}

TY - JOUR

T1 - Single-calcination synthesis of pyrochlore-free Pb(Ni1/3Nb 2/3)O3-PbTiO3 using a coating method

AU - Xiang, Ping Hua

AU - Zhong, Ni

AU - Dong, Xian Lin

PY - 2003/9

Y1 - 2003/9

N2 - Pyrochlore-free 0.64Pb(Ni1/3Nb2/3)O 3-0.36PbTiO3 (0.64PNN-0.36PT) powder has been successfully synthesized by only one calcination step using a coating method. The formation of pyrochlore phase is prevented by coating NiCO 3·2Ni(OH)2·2H2O on Nb 2O5 particles. NiCO3·2Ni(OH) 2·2H2O-coated Nb2O5 powder is prepared by heterogeneous precipitation method. The coating structure is confirmed by transmission electron microscope (TEM) with energy dispersive spectroscope (EDS). Single calcination treatment of the coating powder mixed with appropriate amounts of Pb3O4 and TiO2 powders at 900 °C for 2 h produces the pure-perovskite 0.64PNN-0.36PT powder. The elimination of the pyrochlore phase can be explained in terms of the separating of Pb3O4 and Nb2O5 by the NiCO3·2Ni(OH)2·2H2O coating layer.

AB - Pyrochlore-free 0.64Pb(Ni1/3Nb2/3)O 3-0.36PbTiO3 (0.64PNN-0.36PT) powder has been successfully synthesized by only one calcination step using a coating method. The formation of pyrochlore phase is prevented by coating NiCO 3·2Ni(OH)2·2H2O on Nb 2O5 particles. NiCO3·2Ni(OH) 2·2H2O-coated Nb2O5 powder is prepared by heterogeneous precipitation method. The coating structure is confirmed by transmission electron microscope (TEM) with energy dispersive spectroscope (EDS). Single calcination treatment of the coating powder mixed with appropriate amounts of Pb3O4 and TiO2 powders at 900 °C for 2 h produces the pure-perovskite 0.64PNN-0.36PT powder. The elimination of the pyrochlore phase can be explained in terms of the separating of Pb3O4 and Nb2O5 by the NiCO3·2Ni(OH)2·2H2O coating layer.

KW - A. Ferroelectrics

KW - A. Lead nickel niobate

KW - B. Coating method

KW - C. Morphotropic phase boundary

UR - https://www.scopus.com/pages/publications/0041508441

U2 - 10.1016/S0038-1098(03)00630-6

DO - 10.1016/S0038-1098(03)00630-6

M3 - 文章

AN - SCOPUS:0041508441

SN - 0038-1098

VL - 127

SP - 699

EP - 701

JO - Solid State Communications

JF - Solid State Communications

IS - 11

ER -

Single-calcination synthesis of pyrochlore-free Pb(Ni_1/3Nb _2/3)O₃-PbTiO₃ using a coating method

Abstract

Keywords

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