Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography

Q. Xu; C. Xu; W. Zhang; Y. P. Wang; L. T. Jin; H. Haraguchi; A. Itoh; K. Tanaka

doi:10.1007/BF02492432

Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography

Q. Xu, C. Xu, W. Zhang, Y. P. Wang, L. T. Jin, H. Haraguchi, A. Itoh, K. Tanaka

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A simple, selective and sensitive ion-chromatography method was investigated for simultaneously determining silicic acid, Ca²⁺, Mg²⁺, Al³⁺ and anions (Cl^- and NO₃^-)in real samples. It involved a single-column ion-chromatograph with sodium hydroxide-methanol-water eluent and conductometric detection. Cations were converted to complex anions by adding EDTA to the sample solution. A set of well-defined peaks of silicic acid, Ca²⁺, Mg²⁺, Al³⁺, Cl^- and NO₃^- were obtained. Detection limits using 3.3σ (σ = standard deviation of blank solution) were 1.25 × 10^-6 M for H₃SiO₄^-, 1.32 × 10^-6 M for Ca²⁺, 1.28 × 10^-6 M for Mg²⁺, 1.33 × 10^- 6 M for Al³⁺, 1.31 × 10^-6 M for Cl^- and 1.24 × 10^-6 M for NO₃^-. The method was successfully applied to analysis of mineral water and composite tablets.

Original language	English
Pages (from-to)	81-84
Number of pages	4
Journal	Chromatographia
Volume	53
Issue number	1-2
DOIs	https://doi.org/10.1007/BF02492432
State	Published - 2001

Keywords

Conductometric detection
Ion chromatography
Silicic acid, calcium, magnesium and aluminum
Simultaneous determination

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10.1007/BF02492432

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@article{32010b082c904720904d4003b1e0935e,

title = "Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography",

abstract = "A simple, selective and sensitive ion-chromatography method was investigated for simultaneously determining silicic acid, Ca2+, Mg2+, Al3+ and anions (Cl- and NO3-)in real samples. It involved a single-column ion-chromatograph with sodium hydroxide-methanol-water eluent and conductometric detection. Cations were converted to complex anions by adding EDTA to the sample solution. A set of well-defined peaks of silicic acid, Ca2+, Mg2+, Al3+, Cl- and NO3- were obtained. Detection limits using 3.3σ (σ = standard deviation of blank solution) were 1.25 × 10-6 M for H3SiO4-, 1.32 × 10-6 M for Ca2+, 1.28 × 10-6 M for Mg2+, 1.33 × 10- 6 M for Al3+, 1.31 × 10-6 M for Cl- and 1.24 × 10-6 M for NO3-. The method was successfully applied to analysis of mineral water and composite tablets.",

keywords = "Conductometric detection, Ion chromatography, Silicic acid, calcium, magnesium and aluminum, Simultaneous determination",

author = "Q. Xu and C. Xu and W. Zhang and Wang, \{Y. P.\} and Jin, \{L. T.\} and H. Haraguchi and A. Itoh and K. Tanaka",

year = "2001",

doi = "10.1007/BF02492432",

language = "英语",

volume = "53",

pages = "81--84",

journal = "Chromatographia",

issn = "0009-5893",

publisher = "Springer",

number = "1-2",

}

TY - JOUR

T1 - Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography

AU - Xu, Q.

AU - Xu, C.

AU - Zhang, W.

AU - Wang, Y. P.

AU - Jin, L. T.

AU - Haraguchi, H.

AU - Itoh, A.

AU - Tanaka, K.

PY - 2001

Y1 - 2001

N2 - A simple, selective and sensitive ion-chromatography method was investigated for simultaneously determining silicic acid, Ca2+, Mg2+, Al3+ and anions (Cl- and NO3-)in real samples. It involved a single-column ion-chromatograph with sodium hydroxide-methanol-water eluent and conductometric detection. Cations were converted to complex anions by adding EDTA to the sample solution. A set of well-defined peaks of silicic acid, Ca2+, Mg2+, Al3+, Cl- and NO3- were obtained. Detection limits using 3.3σ (σ = standard deviation of blank solution) were 1.25 × 10-6 M for H3SiO4-, 1.32 × 10-6 M for Ca2+, 1.28 × 10-6 M for Mg2+, 1.33 × 10- 6 M for Al3+, 1.31 × 10-6 M for Cl- and 1.24 × 10-6 M for NO3-. The method was successfully applied to analysis of mineral water and composite tablets.

AB - A simple, selective and sensitive ion-chromatography method was investigated for simultaneously determining silicic acid, Ca2+, Mg2+, Al3+ and anions (Cl- and NO3-)in real samples. It involved a single-column ion-chromatograph with sodium hydroxide-methanol-water eluent and conductometric detection. Cations were converted to complex anions by adding EDTA to the sample solution. A set of well-defined peaks of silicic acid, Ca2+, Mg2+, Al3+, Cl- and NO3- were obtained. Detection limits using 3.3σ (σ = standard deviation of blank solution) were 1.25 × 10-6 M for H3SiO4-, 1.32 × 10-6 M for Ca2+, 1.28 × 10-6 M for Mg2+, 1.33 × 10- 6 M for Al3+, 1.31 × 10-6 M for Cl- and 1.24 × 10-6 M for NO3-. The method was successfully applied to analysis of mineral water and composite tablets.

KW - Conductometric detection

KW - Ion chromatography

KW - Silicic acid, calcium, magnesium and aluminum

KW - Simultaneous determination

UR - https://www.scopus.com/pages/publications/0035091681

U2 - 10.1007/BF02492432

DO - 10.1007/BF02492432

M3 - 文章

AN - SCOPUS:0035091681

SN - 0009-5893

VL - 53

SP - 81

EP - 84

JO - Chromatographia

JF - Chromatographia

IS - 1-2

ER -

Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography

Abstract

Keywords

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