Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography

Q. Xu; C. Xu; W. Zhang; Y. P. Wang; L. T. Jin; H. Haraguchi; A. Itoh; K. Tanaka

doi:10.1007/BF02492432

Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography

Q. Xu
, C. Xu
, W. Zhang
, Y. P. Wang
, L. T. Jin^*
, H. Haraguchi
, A. Itoh
, K. Tanaka

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
Nagoya University
National Institute of Advanced Industrial Science and Technology

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A simple, selective and sensitive ion-chromatography method was investigated for simultaneously determining silicic acid, Ca²⁺, Mg²⁺, Al³⁺ and anions (Cl^- and NO₃^-)in real samples. It involved a single-column ion-chromatograph with sodium hydroxide-methanol-water eluent and conductometric detection. Cations were converted to complex anions by adding EDTA to the sample solution. A set of well-defined peaks of silicic acid, Ca²⁺, Mg²⁺, Al³⁺, Cl^- and NO₃^- were obtained. Detection limits using 3.3σ (σ = standard deviation of blank solution) were 1.25 × 10^-6 M for H₃SiO₄^-, 1.32 × 10^-6 M for Ca²⁺, 1.28 × 10^-6 M for Mg²⁺, 1.33 × 10^- 6 M for Al³⁺, 1.31 × 10^-6 M for Cl^- and 1.24 × 10^-6 M for NO₃^-. The method was successfully applied to analysis of mineral water and composite tablets.

Original language	English
Pages (from-to)	81-84
Number of pages	4
Journal	Chromatographia
Volume	53
Issue number	1-2
DOIs	https://doi.org/10.1007/BF02492432
State	Published - 2001

Keywords

Conductometric detection
Ion chromatography
Silicic acid, calcium, magnesium and aluminum
Simultaneous determination

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10.1007/BF02492432

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@article{32010b082c904720904d4003b1e0935e,

title = "Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography",

abstract = "A simple, selective and sensitive ion-chromatography method was investigated for simultaneously determining silicic acid, Ca2+, Mg2+, Al3+ and anions (Cl- and NO3-)in real samples. It involved a single-column ion-chromatograph with sodium hydroxide-methanol-water eluent and conductometric detection. Cations were converted to complex anions by adding EDTA to the sample solution. A set of well-defined peaks of silicic acid, Ca2+, Mg2+, Al3+, Cl- and NO3- were obtained. Detection limits using 3.3σ (σ = standard deviation of blank solution) were 1.25 × 10-6 M for H3SiO4-, 1.32 × 10-6 M for Ca2+, 1.28 × 10-6 M for Mg2+, 1.33 × 10- 6 M for Al3+, 1.31 × 10-6 M for Cl- and 1.24 × 10-6 M for NO3-. The method was successfully applied to analysis of mineral water and composite tablets.",

keywords = "Conductometric detection, Ion chromatography, Silicic acid, calcium, magnesium and aluminum, Simultaneous determination",

author = "Q. Xu and C. Xu and W. Zhang and Wang, \{Y. P.\} and Jin, \{L. T.\} and H. Haraguchi and A. Itoh and K. Tanaka",

year = "2001",

doi = "10.1007/BF02492432",

language = "英语",

volume = "53",

pages = "81--84",

journal = "Chromatographia",

issn = "0009-5893",

publisher = "Springer",

number = "1-2",

}

TY - JOUR

T1 - Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography

AU - Xu, Q.

AU - Xu, C.

AU - Zhang, W.

AU - Wang, Y. P.

AU - Jin, L. T.

AU - Haraguchi, H.

AU - Itoh, A.

AU - Tanaka, K.

PY - 2001

Y1 - 2001

N2 - A simple, selective and sensitive ion-chromatography method was investigated for simultaneously determining silicic acid, Ca2+, Mg2+, Al3+ and anions (Cl- and NO3-)in real samples. It involved a single-column ion-chromatograph with sodium hydroxide-methanol-water eluent and conductometric detection. Cations were converted to complex anions by adding EDTA to the sample solution. A set of well-defined peaks of silicic acid, Ca2+, Mg2+, Al3+, Cl- and NO3- were obtained. Detection limits using 3.3σ (σ = standard deviation of blank solution) were 1.25 × 10-6 M for H3SiO4-, 1.32 × 10-6 M for Ca2+, 1.28 × 10-6 M for Mg2+, 1.33 × 10- 6 M for Al3+, 1.31 × 10-6 M for Cl- and 1.24 × 10-6 M for NO3-. The method was successfully applied to analysis of mineral water and composite tablets.

AB - A simple, selective and sensitive ion-chromatography method was investigated for simultaneously determining silicic acid, Ca2+, Mg2+, Al3+ and anions (Cl- and NO3-)in real samples. It involved a single-column ion-chromatograph with sodium hydroxide-methanol-water eluent and conductometric detection. Cations were converted to complex anions by adding EDTA to the sample solution. A set of well-defined peaks of silicic acid, Ca2+, Mg2+, Al3+, Cl- and NO3- were obtained. Detection limits using 3.3σ (σ = standard deviation of blank solution) were 1.25 × 10-6 M for H3SiO4-, 1.32 × 10-6 M for Ca2+, 1.28 × 10-6 M for Mg2+, 1.33 × 10- 6 M for Al3+, 1.31 × 10-6 M for Cl- and 1.24 × 10-6 M for NO3-. The method was successfully applied to analysis of mineral water and composite tablets.

KW - Conductometric detection

KW - Ion chromatography

KW - Silicic acid, calcium, magnesium and aluminum

KW - Simultaneous determination

UR - https://www.scopus.com/pages/publications/0035091681

U2 - 10.1007/BF02492432

DO - 10.1007/BF02492432

M3 - 文章

AN - SCOPUS:0035091681

SN - 0009-5893

VL - 53

SP - 81

EP - 84

JO - Chromatographia

JF - Chromatographia

IS - 1-2

ER -

Simultaneous determination of silicic acid, Ca, Mg and Al in mineral water and composite tablets by ion chromatography

Abstract

Keywords

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