Silica-sheathed pyrrotite nanowires: Synthesis and mechanism

Hao Xu Zhang; Jian Ping Ge; Jin Wang; Zhe Wang; Da Peng Yu; Ya Dong Li

doi:10.1021/jp051142o

Silica-sheathed pyrrotite nanowires: Synthesis and mechanism

Hao Xu Zhang
, Jian Ping Ge
, Jin Wang
, Zhe Wang
, Da Peng Yu
, Ya Dong Li^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

We have studied the growth of silica-sheathed 3C-Fe₇S ₈ products on silicon substrates with FeCl₂ and sulfur precursors at the temperature region of 600-800°C. On the basis of the crystal structure of Fe₇S₈, we have proposed a model including the kinetic competition of the adsorption of silica species on Fe2-Fe3-Fe4 units at the 4Fe layer and on the Fe2-Fe3-Fe4-Fe5 units parallel to the c-axis. Using this model, we have not only explained all the experimental phenomena but also especially prepared Fe₇S₈ nanowires at 650°C by introducing water into the reaction system.

Original language	English
Pages (from-to)	11585-11591
Number of pages	7
Journal	Journal of Physical Chemistry B
Volume	109
Issue number	23
DOIs	https://doi.org/10.1021/jp051142o
State	Published - 16 Jun 2005
Externally published	Yes

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@article{b8bdc19d79cf49bfb8a01e8f27c915b2,

title = "Silica-sheathed pyrrotite nanowires: Synthesis and mechanism",

abstract = "We have studied the growth of silica-sheathed 3C-Fe7S 8 products on silicon substrates with FeCl2 and sulfur precursors at the temperature region of 600-800°C. On the basis of the crystal structure of Fe7S8, we have proposed a model including the kinetic competition of the adsorption of silica species on Fe2-Fe3-Fe4 units at the 4Fe layer and on the Fe2-Fe3-Fe4-Fe5 units parallel to the c-axis. Using this model, we have not only explained all the experimental phenomena but also especially prepared Fe7S8 nanowires at 650°C by introducing water into the reaction system.",

author = "Zhang, \{Hao Xu\} and Ge, \{Jian Ping\} and Jin Wang and Zhe Wang and Yu, \{Da Peng\} and Li, \{Ya Dong\}",

year = "2005",

month = jun,

day = "16",

doi = "10.1021/jp051142o",

language = "英语",

volume = "109",

pages = "11585--11591",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - Silica-sheathed pyrrotite nanowires

T2 - Synthesis and mechanism

AU - Zhang, Hao Xu

AU - Ge, Jian Ping

AU - Wang, Jin

AU - Wang, Zhe

AU - Yu, Da Peng

AU - Li, Ya Dong

PY - 2005/6/16

Y1 - 2005/6/16

N2 - We have studied the growth of silica-sheathed 3C-Fe7S 8 products on silicon substrates with FeCl2 and sulfur precursors at the temperature region of 600-800°C. On the basis of the crystal structure of Fe7S8, we have proposed a model including the kinetic competition of the adsorption of silica species on Fe2-Fe3-Fe4 units at the 4Fe layer and on the Fe2-Fe3-Fe4-Fe5 units parallel to the c-axis. Using this model, we have not only explained all the experimental phenomena but also especially prepared Fe7S8 nanowires at 650°C by introducing water into the reaction system.

AB - We have studied the growth of silica-sheathed 3C-Fe7S 8 products on silicon substrates with FeCl2 and sulfur precursors at the temperature region of 600-800°C. On the basis of the crystal structure of Fe7S8, we have proposed a model including the kinetic competition of the adsorption of silica species on Fe2-Fe3-Fe4 units at the 4Fe layer and on the Fe2-Fe3-Fe4-Fe5 units parallel to the c-axis. Using this model, we have not only explained all the experimental phenomena but also especially prepared Fe7S8 nanowires at 650°C by introducing water into the reaction system.

UR - https://www.scopus.com/pages/publications/21644459944

U2 - 10.1021/jp051142o

DO - 10.1021/jp051142o

M3 - 文章

AN - SCOPUS:21644459944

SN - 1520-6106

VL - 109

SP - 11585

EP - 11591

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 23

ER -

Silica-sheathed pyrrotite nanowires: Synthesis and mechanism

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