Self-Doping a Hole-Transporting Layer Based on a Conjugated Polyelectrolyte Enables Efficient and Stable Inverted Perovskite Solar Cells

Shuang Li; Li Wan; Lijun Chen; Changbo Deng; Lupiao Tao; Zhanpeng Lu; Wenjun Zhang; Junfeng Fang; Weijie Song

doi:10.1021/acsaem.0c01827

Self-Doping a Hole-Transporting Layer Based on a Conjugated Polyelectrolyte Enables Efficient and Stable Inverted Perovskite Solar Cells

Shuang Li
, Li Wan
, Lijun Chen
, Changbo Deng
, Lupiao Tao
, Zhanpeng Lu
, Wenjun Zhang^*
, Junfeng Fang^*
, Weijie Song

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The interface material is an indispensable part of perovskite solar cells (PSCs) because of its special functions. In this work, a conjugated polyelectrolyte, PTPADT-SO3Na, was synthesized and introduced to the inverted PSCs as a hole-transporting layer (HTL). PTPADT-SO3Na exhibits a close level of valence band to perovskites and good conductivity because of a self-doping effect. Accordingly, the PTPADT-SO3Na device shows excellent performances with a maximum efficiency of 18.15%, which is better than that of the device with a typical HTL [poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)]. Meanwhile, the PTPADT-SO3Na PSC exhibits outstanding stability in an ambient atmosphere (humidity of 50%) and heating condition (85 °C).

Original language	English
Pages (from-to)	11724-11731
Number of pages	8
Journal	ACS Applied Energy Materials
Volume	3
Issue number	12
DOIs	https://doi.org/10.1021/acsaem.0c01827
State	Published - 28 Dec 2020
Externally published	Yes

Keywords

High performance
Interface
Inverted perovskite solar cell
P-type conjugated polymer
Self-doping effect

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10.1021/acsaem.0c01827

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@article{9c39331eee3d49ea87c87abdfc9bacfe,

title = "Self-Doping a Hole-Transporting Layer Based on a Conjugated Polyelectrolyte Enables Efficient and Stable Inverted Perovskite Solar Cells",

abstract = "The interface material is an indispensable part of perovskite solar cells (PSCs) because of its special functions. In this work, a conjugated polyelectrolyte, PTPADT-SO3Na, was synthesized and introduced to the inverted PSCs as a hole-transporting layer (HTL). PTPADT-SO3Na exhibits a close level of valence band to perovskites and good conductivity because of a self-doping effect. Accordingly, the PTPADT-SO3Na device shows excellent performances with a maximum efficiency of 18.15\%, which is better than that of the device with a typical HTL [poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)]. Meanwhile, the PTPADT-SO3Na PSC exhibits outstanding stability in an ambient atmosphere (humidity of 50\%) and heating condition (85 °C).",

keywords = "High performance, Interface, Inverted perovskite solar cell, P-type conjugated polymer, Self-doping effect",

author = "Shuang Li and Li Wan and Lijun Chen and Changbo Deng and Lupiao Tao and Zhanpeng Lu and Wenjun Zhang and Junfeng Fang and Weijie Song",

note = "Publisher Copyright: {\textcopyright} ",

year = "2020",

month = dec,

day = "28",

doi = "10.1021/acsaem.0c01827",

language = "英语",

volume = "3",

pages = "11724--11731",

journal = "ACS Applied Energy Materials",

issn = "2574-0962",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Self-Doping a Hole-Transporting Layer Based on a Conjugated Polyelectrolyte Enables Efficient and Stable Inverted Perovskite Solar Cells

AU - Li, Shuang

AU - Wan, Li

AU - Chen, Lijun

AU - Deng, Changbo

AU - Tao, Lupiao

AU - Lu, Zhanpeng

AU - Zhang, Wenjun

AU - Fang, Junfeng

AU - Song, Weijie

N1 - Publisher Copyright: ©

PY - 2020/12/28

Y1 - 2020/12/28

N2 - The interface material is an indispensable part of perovskite solar cells (PSCs) because of its special functions. In this work, a conjugated polyelectrolyte, PTPADT-SO3Na, was synthesized and introduced to the inverted PSCs as a hole-transporting layer (HTL). PTPADT-SO3Na exhibits a close level of valence band to perovskites and good conductivity because of a self-doping effect. Accordingly, the PTPADT-SO3Na device shows excellent performances with a maximum efficiency of 18.15%, which is better than that of the device with a typical HTL [poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)]. Meanwhile, the PTPADT-SO3Na PSC exhibits outstanding stability in an ambient atmosphere (humidity of 50%) and heating condition (85 °C).

AB - The interface material is an indispensable part of perovskite solar cells (PSCs) because of its special functions. In this work, a conjugated polyelectrolyte, PTPADT-SO3Na, was synthesized and introduced to the inverted PSCs as a hole-transporting layer (HTL). PTPADT-SO3Na exhibits a close level of valence band to perovskites and good conductivity because of a self-doping effect. Accordingly, the PTPADT-SO3Na device shows excellent performances with a maximum efficiency of 18.15%, which is better than that of the device with a typical HTL [poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)]. Meanwhile, the PTPADT-SO3Na PSC exhibits outstanding stability in an ambient atmosphere (humidity of 50%) and heating condition (85 °C).

KW - High performance

KW - Interface

KW - Inverted perovskite solar cell

KW - P-type conjugated polymer

KW - Self-doping effect

UR - https://www.scopus.com/pages/publications/85097816584

U2 - 10.1021/acsaem.0c01827

DO - 10.1021/acsaem.0c01827

M3 - 文章

AN - SCOPUS:85097816584

SN - 2574-0962

VL - 3

SP - 11724

EP - 11731

JO - ACS Applied Energy Materials

JF - ACS Applied Energy Materials

IS - 12

ER -

Self-Doping a Hole-Transporting Layer Based on a Conjugated Polyelectrolyte Enables Efficient and Stable Inverted Perovskite Solar Cells

Abstract

Keywords

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