Selective Hydrogenolysis of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran under Mild Conditions Using Pd/MOF-808

Kaili Zhang; Qinglei Meng; Haihong Wu; Mingyuan He; Buxing Han

doi:10.1021/acssuschemeng.2c02393

Selective Hydrogenolysis of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran under Mild Conditions Using Pd/MOF-808

Kaili Zhang
, Qinglei Meng
, Haihong Wu^*
, Mingyuan He
, Buxing Han^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
Institute of Eco-Chongming
CAS - Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

2,5-Dimethylfuran (DMF) is an important candidate for liquid fuels, which can be produced from biomass-derived 5-hydroxymethylfurfural (5-HMF). Efficient catalysts for selective hydrogenolysis of HMF to DMF under mild conditions without any additives are highly desired. Herein, we designed and prepared a Zr-based metal-organic framework (MOF-808) supported Pd catalyst (Pd/MOF-808), which can efficiently catalyze the hydrogenolysis of HMF to DMF with a yield of 99% under 100 °C without any additives. In addition, the Pd/MOF-808 catalyst also showed good reusability, with the capability of being used five times without loss of activity.

Original language	English
Pages (from-to)	10286-10293
Number of pages	8
Journal	ACS Sustainable Chemistry and Engineering
Volume	10
Issue number	31
DOIs	https://doi.org/10.1021/acssuschemeng.2c02393
State	Published - 8 Aug 2022

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

2,5-Dimethyl furan (DMF)
5-Hydroxymethylfurfural (HMF)
Biomass
Green chemistry
Hydrogenolysis
Palladium

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10.1021/acssuschemeng.2c02393

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title = "Selective Hydrogenolysis of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran under Mild Conditions Using Pd/MOF-808",

abstract = "2,5-Dimethylfuran (DMF) is an important candidate for liquid fuels, which can be produced from biomass-derived 5-hydroxymethylfurfural (5-HMF). Efficient catalysts for selective hydrogenolysis of HMF to DMF under mild conditions without any additives are highly desired. Herein, we designed and prepared a Zr-based metal-organic framework (MOF-808) supported Pd catalyst (Pd/MOF-808), which can efficiently catalyze the hydrogenolysis of HMF to DMF with a yield of 99\% under 100 °C without any additives. In addition, the Pd/MOF-808 catalyst also showed good reusability, with the capability of being used five times without loss of activity.",

keywords = "2,5-Dimethyl furan (DMF), 5-Hydroxymethylfurfural (HMF), Biomass, Green chemistry, Hydrogenolysis, Palladium",

author = "Kaili Zhang and Qinglei Meng and Haihong Wu and Mingyuan He and Buxing Han",

note = "Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",

year = "2022",

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day = "8",

doi = "10.1021/acssuschemeng.2c02393",

language = "英语",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Selective Hydrogenolysis of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran under Mild Conditions Using Pd/MOF-808

AU - Zhang, Kaili

AU - Meng, Qinglei

AU - Wu, Haihong

AU - He, Mingyuan

AU - Han, Buxing

PY - 2022/8/8

Y1 - 2022/8/8

N2 - 2,5-Dimethylfuran (DMF) is an important candidate for liquid fuels, which can be produced from biomass-derived 5-hydroxymethylfurfural (5-HMF). Efficient catalysts for selective hydrogenolysis of HMF to DMF under mild conditions without any additives are highly desired. Herein, we designed and prepared a Zr-based metal-organic framework (MOF-808) supported Pd catalyst (Pd/MOF-808), which can efficiently catalyze the hydrogenolysis of HMF to DMF with a yield of 99% under 100 °C without any additives. In addition, the Pd/MOF-808 catalyst also showed good reusability, with the capability of being used five times without loss of activity.

AB - 2,5-Dimethylfuran (DMF) is an important candidate for liquid fuels, which can be produced from biomass-derived 5-hydroxymethylfurfural (5-HMF). Efficient catalysts for selective hydrogenolysis of HMF to DMF under mild conditions without any additives are highly desired. Herein, we designed and prepared a Zr-based metal-organic framework (MOF-808) supported Pd catalyst (Pd/MOF-808), which can efficiently catalyze the hydrogenolysis of HMF to DMF with a yield of 99% under 100 °C without any additives. In addition, the Pd/MOF-808 catalyst also showed good reusability, with the capability of being used five times without loss of activity.

KW - 2,5-Dimethyl furan (DMF)

KW - 5-Hydroxymethylfurfural (HMF)

KW - Biomass

KW - Green chemistry

KW - Hydrogenolysis

KW - Palladium

UR - https://www.scopus.com/pages/publications/85136141106

U2 - 10.1021/acssuschemeng.2c02393

DO - 10.1021/acssuschemeng.2c02393

M3 - 文章

AN - SCOPUS:85136141106

SN - 2168-0485

VL - 10

SP - 10286

EP - 10293

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 31

ER -

Selective Hydrogenolysis of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran under Mild Conditions Using Pd/MOF-808

Abstract

UN SDGs

Keywords

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