Selective chemochromic and chemically-induced photochromic response of a metal-organic framework

Peng Li; Qi Sui; Meng Yue Guo; Shuai Liang Yang; Ran Bu; En Qing Gao

doi:10.1039/d0cc01627f

Selective chemochromic and chemically-induced photochromic response of a metal-organic framework

Peng Li
, Qi Sui
, Meng Yue Guo
, Shuai Liang Yang
, Ran Bu
, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

The Zn(ii) MOF with a tripyridinium-based hexacarboxylate shows direct color change on exposure to small primary amines and UV-assisted color response on exposure to small alcohols. The reversible, group-specific and size-selective chemochromic/chemophotochromic behaviours are ascribed to spontaneous/photoinduced guest-to-host electron transfer within the unique confined space furnished with electron-deficient sites.

Original language	English
Pages (from-to)	5929-5932
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	44
DOIs	https://doi.org/10.1039/d0cc01627f
State	Published - 4 Jun 2020

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title = "Selective chemochromic and chemically-induced photochromic response of a metal-organic framework",

abstract = "The Zn(ii) MOF with a tripyridinium-based hexacarboxylate shows direct color change on exposure to small primary amines and UV-assisted color response on exposure to small alcohols. The reversible, group-specific and size-selective chemochromic/chemophotochromic behaviours are ascribed to spontaneous/photoinduced guest-to-host electron transfer within the unique confined space furnished with electron-deficient sites.",

author = "Peng Li and Qi Sui and Guo, \{Meng Yue\} and Yang, \{Shuai Liang\} and Ran Bu and Gao, \{En Qing\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2020.",

year = "2020",

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doi = "10.1039/d0cc01627f",

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T1 - Selective chemochromic and chemically-induced photochromic response of a metal-organic framework

AU - Li, Peng

AU - Sui, Qi

AU - Guo, Meng Yue

AU - Yang, Shuai Liang

AU - Bu, Ran

AU - Gao, En Qing

PY - 2020/6/4

Y1 - 2020/6/4

N2 - The Zn(ii) MOF with a tripyridinium-based hexacarboxylate shows direct color change on exposure to small primary amines and UV-assisted color response on exposure to small alcohols. The reversible, group-specific and size-selective chemochromic/chemophotochromic behaviours are ascribed to spontaneous/photoinduced guest-to-host electron transfer within the unique confined space furnished with electron-deficient sites.

AB - The Zn(ii) MOF with a tripyridinium-based hexacarboxylate shows direct color change on exposure to small primary amines and UV-assisted color response on exposure to small alcohols. The reversible, group-specific and size-selective chemochromic/chemophotochromic behaviours are ascribed to spontaneous/photoinduced guest-to-host electron transfer within the unique confined space furnished with electron-deficient sites.

UR - https://www.scopus.com/pages/publications/85085643659

U2 - 10.1039/d0cc01627f

DO - 10.1039/d0cc01627f

M3 - 文章

C2 - 32342972

AN - SCOPUS:85085643659

SN - 1359-7345

VL - 56

SP - 5929

EP - 5932

JO - Chemical Communications

JF - Chemical Communications

IS - 44

ER -

Selective chemochromic and chemically-induced photochromic response of a metal-organic framework

Abstract

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