Rotational analysis of A 2Πu- X 2Πg system of 16O2+ cation

  • Jing Zhang
  • , Yuan Yue Zhu
  • , Lun Hua Deng*
  • , Yang Qin Chen
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The Doppler-limited absorption spectrum of 16O2 + cation was observed in the region of 11385-12100 cm-1 by optical heterodyne velocity modulation absorption spectroscopy (OH-VMS). The transitions were assigned to the (2, 19), (3, 20), and (5, 21) bands in the second negative system (A2Πu-X2Π g). All the available lines measured using OH-VMS were global fitted in a nonlinear least-squares fitting procedure, and precise molecular constants (Bv, Av, Dv, pv, qv, γv) were obtained for the involved levels.

Original languageEnglish
Pages (from-to)137-143
Number of pages7
JournalChinese Journal of Chemical Physics
Volume27
Issue number2
DOIs
StatePublished - 27 Apr 2014

Keywords

  • Oxygen molecule cation
  • Rotational resolution
  • Second negative system

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