Room temperature hydrogenation of furfuryl alcohol by Pd/titanate nanotube

Qingqing Yuan; Feiyang Ye; Teng Xue; Yejun Guan

doi:10.1016/j.apcata.2015.09.034

Room temperature hydrogenation of furfuryl alcohol by Pd/titanate nanotube

Qingqing Yuan
, Feiyang Ye
, Teng Xue
, Yejun Guan^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The liquid phase hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol at room temperature under 1 atm hydrogen was succeeded on a TiO₂ nanotube (TNT) supported palladium catalyst. The palladium nanoparticles in size of 2-8 nm were loaded by the deposition-reduction method with NaBH₄ as reducing reagent. The Pd/TNT catalyst showed high dispersion as revealed by CO chemisorption and improved catalytic performance in terms of both furfuryl alcohol conversion and tetrahydrofurfuryl alcohol selectivity, probably attributed to the unique electronic interaction between Pd metals and TNT surface containing sodium cations. Among the catalysts investigated, 5.8 wt.% Pd/TNT showed the best performance, with 98% conversion and 98% selectivity to tetrahydrofurfuryl alcohol in ethanol.

Original language	English
Article number	15566
Pages (from-to)	26-33
Number of pages	8
Journal	Applied Catalysis A: General
Volume	507
DOIs	https://doi.org/10.1016/j.apcata.2015.09.034
State	Published - 25 Oct 2015

Keywords

Furfuryl alcohol
Hydrogenation
Palladium
Tetrahydrofurfuryl alcohol
Titanate nanotube

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10.1016/j.apcata.2015.09.034

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title = "Room temperature hydrogenation of furfuryl alcohol by Pd/titanate nanotube",

abstract = "The liquid phase hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol at room temperature under 1 atm hydrogen was succeeded on a TiO2 nanotube (TNT) supported palladium catalyst. The palladium nanoparticles in size of 2-8 nm were loaded by the deposition-reduction method with NaBH4 as reducing reagent. The Pd/TNT catalyst showed high dispersion as revealed by CO chemisorption and improved catalytic performance in terms of both furfuryl alcohol conversion and tetrahydrofurfuryl alcohol selectivity, probably attributed to the unique electronic interaction between Pd metals and TNT surface containing sodium cations. Among the catalysts investigated, 5.8 wt.\% Pd/TNT showed the best performance, with 98\% conversion and 98\% selectivity to tetrahydrofurfuryl alcohol in ethanol.",

keywords = "Furfuryl alcohol, Hydrogenation, Palladium, Tetrahydrofurfuryl alcohol, Titanate nanotube",

author = "Qingqing Yuan and Feiyang Ye and Teng Xue and Yejun Guan",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2015",

month = oct,

day = "25",

doi = "10.1016/j.apcata.2015.09.034",

language = "英语",

volume = "507",

pages = "26--33",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

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TY - JOUR

T1 - Room temperature hydrogenation of furfuryl alcohol by Pd/titanate nanotube

AU - Yuan, Qingqing

AU - Ye, Feiyang

AU - Xue, Teng

AU - Guan, Yejun

PY - 2015/10/25

Y1 - 2015/10/25

N2 - The liquid phase hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol at room temperature under 1 atm hydrogen was succeeded on a TiO2 nanotube (TNT) supported palladium catalyst. The palladium nanoparticles in size of 2-8 nm were loaded by the deposition-reduction method with NaBH4 as reducing reagent. The Pd/TNT catalyst showed high dispersion as revealed by CO chemisorption and improved catalytic performance in terms of both furfuryl alcohol conversion and tetrahydrofurfuryl alcohol selectivity, probably attributed to the unique electronic interaction between Pd metals and TNT surface containing sodium cations. Among the catalysts investigated, 5.8 wt.% Pd/TNT showed the best performance, with 98% conversion and 98% selectivity to tetrahydrofurfuryl alcohol in ethanol.

AB - The liquid phase hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol at room temperature under 1 atm hydrogen was succeeded on a TiO2 nanotube (TNT) supported palladium catalyst. The palladium nanoparticles in size of 2-8 nm were loaded by the deposition-reduction method with NaBH4 as reducing reagent. The Pd/TNT catalyst showed high dispersion as revealed by CO chemisorption and improved catalytic performance in terms of both furfuryl alcohol conversion and tetrahydrofurfuryl alcohol selectivity, probably attributed to the unique electronic interaction between Pd metals and TNT surface containing sodium cations. Among the catalysts investigated, 5.8 wt.% Pd/TNT showed the best performance, with 98% conversion and 98% selectivity to tetrahydrofurfuryl alcohol in ethanol.

KW - Furfuryl alcohol

KW - Hydrogenation

KW - Palladium

KW - Tetrahydrofurfuryl alcohol

KW - Titanate nanotube

UR - https://www.scopus.com/pages/publications/84943246624

U2 - 10.1016/j.apcata.2015.09.034

DO - 10.1016/j.apcata.2015.09.034

M3 - 文章

AN - SCOPUS:84943246624

SN - 0926-860X

VL - 507

SP - 26

EP - 33

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

M1 - 15566

ER -

Room temperature hydrogenation of furfuryl alcohol by Pd/titanate nanotube

Abstract

Keywords

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