Ring-opening of cyclic anhydrides using ionic liquids

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Abstract

Four novel Brønsted acidic ionic liquids with two different acid sites on the imidazolium cations were synthesised and employed as catalysts and solvents for the ring-opening of cyclic anhydrides to synthesise half-esters. The results showed that these novel Brønsted acidic ionic liquids were efficient and recyclable. Good yields, short reaction times and mild reaction conditions were achieved.

Original languageEnglish
Pages (from-to)167-169
Number of pages3
JournalJournal of Chemical Research
Issue number3
DOIs
StatePublished - Mar 2009

Keywords

  • Cyclic anhydride
  • Half-ester
  • Ionic liquid
  • Ring-opening

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