Abstract
A new rhodamine-based derivative modified with allyl group, RPd4, was synthesized as fluorescence-enhanced probe with excellent selectivity for Pd2+ and good anti-jamming ability over other cations. The fluorescence intensitiy was linearly proportional to the amount of Pd2+ added in μmol/L level with a detection limit of 0.51μmol/L. With the pKa of 3.81 ± 0.02, it can be used for Pd2+ detection in neutral pH range. The colorimetric and fluorimetric response between RPd4 and Pd2+ can provide a convenient method for visual detection of Pd2+.
| Original language | English |
|---|---|
| Pages (from-to) | 1725-1728 |
| Number of pages | 4 |
| Journal | Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities |
| Volume | 31 |
| Issue number | 9 |
| State | Published - Sep 2010 |
| Externally published | Yes |
Keywords
- Allyl
- Fluorescence probe
- Fluorescence-enhanced
- Rhodamine