RhCl(PPh3)3/DPPF: A useful and efficient catalyst for cross-coupling reactions of activated alkenyl tosylates with arylboronic acids

Jie Wu; Liang Zhang; Ke Gao

doi:10.1002/ejoc.200600469

RhCl(PPh₃)₃/DPPF: A useful and efficient catalyst for cross-coupling reactions of activated alkenyl tosylates with arylboronic acids

Jie Wu^*
, Liang Zhang
, Ke Gao

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

A useful and effective rhodium catalyst system - [RhCl(PPh ₃)₃/DPPF] - for the Suzuki-Miyaura cross-coupling of activated alkenyl tosylates is described. The results not only represent the first examples of the rhodium-catalyzed Suzuki-Miyaura coupling of activated alkenyl tosylates with arylboronic acids under mild conditions, but also provide an efficient route for the synthesis of some natural product-like compounds, such as furan-2(5H)-one, coumarin, pyrone, and quinolin-2(1H)-one derivatives.

Original language	English
Pages (from-to)	5260-5263
Number of pages	4
Journal	European Journal of Organic Chemistry
Issue number	23
DOIs	https://doi.org/10.1002/ejoc.200600469
State	Published - 27 Nov 2006
Externally published	Yes

Keywords

1,1′-bis(diphenylphosphanyl)ferrocene
Activated alkenyl tosylates
Cross-coupling
Natural product-like compounds
Rhodium

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10.1002/ejoc.200600469

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title = "RhCl(PPh3)3/DPPF: A useful and efficient catalyst for cross-coupling reactions of activated alkenyl tosylates with arylboronic acids",

abstract = "A useful and effective rhodium catalyst system - [RhCl(PPh 3)3/DPPF] - for the Suzuki-Miyaura cross-coupling of activated alkenyl tosylates is described. The results not only represent the first examples of the rhodium-catalyzed Suzuki-Miyaura coupling of activated alkenyl tosylates with arylboronic acids under mild conditions, but also provide an efficient route for the synthesis of some natural product-like compounds, such as furan-2(5H)-one, coumarin, pyrone, and quinolin-2(1H)-one derivatives.",

keywords = "1,1′-bis(diphenylphosphanyl)ferrocene, Activated alkenyl tosylates, Cross-coupling, Natural product-like compounds, Rhodium",

author = "Jie Wu and Liang Zhang and Ke Gao",

year = "2006",

month = nov,

day = "27",

doi = "10.1002/ejoc.200600469",

language = "英语",

pages = "5260--5263",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-VCH Verlag",

number = "23",

}

TY - JOUR

T1 - RhCl(PPh3)3/DPPF

T2 - A useful and efficient catalyst for cross-coupling reactions of activated alkenyl tosylates with arylboronic acids

AU - Wu, Jie

AU - Zhang, Liang

AU - Gao, Ke

PY - 2006/11/27

Y1 - 2006/11/27

N2 - A useful and effective rhodium catalyst system - [RhCl(PPh 3)3/DPPF] - for the Suzuki-Miyaura cross-coupling of activated alkenyl tosylates is described. The results not only represent the first examples of the rhodium-catalyzed Suzuki-Miyaura coupling of activated alkenyl tosylates with arylboronic acids under mild conditions, but also provide an efficient route for the synthesis of some natural product-like compounds, such as furan-2(5H)-one, coumarin, pyrone, and quinolin-2(1H)-one derivatives.

AB - A useful and effective rhodium catalyst system - [RhCl(PPh 3)3/DPPF] - for the Suzuki-Miyaura cross-coupling of activated alkenyl tosylates is described. The results not only represent the first examples of the rhodium-catalyzed Suzuki-Miyaura coupling of activated alkenyl tosylates with arylboronic acids under mild conditions, but also provide an efficient route for the synthesis of some natural product-like compounds, such as furan-2(5H)-one, coumarin, pyrone, and quinolin-2(1H)-one derivatives.

KW - 1,1′-bis(diphenylphosphanyl)ferrocene

KW - Activated alkenyl tosylates

KW - Cross-coupling

KW - Natural product-like compounds

KW - Rhodium

UR - https://www.scopus.com/pages/publications/33845438492

U2 - 10.1002/ejoc.200600469

DO - 10.1002/ejoc.200600469

M3 - 文章

AN - SCOPUS:33845438492

SN - 1434-193X

SP - 5260

EP - 5263

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 23

ER -

RhCl(PPh₃)₃/DPPF: A useful and efficient catalyst for cross-coupling reactions of activated alkenyl tosylates with arylboronic acids

Abstract

Keywords

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