Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal-organic framework with high capacity

Tian Li; Chao Li; Xiaoshi Hu; Xiaobing Lou; Huiping Hu; Likun Pan; Qun Chen; Ming Shen; Bingwen Hu

doi:10.1039/c6ra07727g

Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal-organic framework with high capacity

Tian Li, Chao Li, Xiaoshi Hu, Xiaobing Lou, Huiping Hu, Likun Pan, Qun Chen, Ming Shen, Bingwen Hu

East China Normal University

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Metal-organic frameworks (MOFs), are explosively developed as electrode materials for lithium-ion batteries. Mn-BTC MOF possessed low cycling stability. We therefore attempted to improve the electrochemical properties by doping cobalt into the Mn-BTC. Cobalt doped MnCo-BTC MOF greatly improved the cycling stability compared with Mn-BTC. A high capacity of 901 mA h g^-1 could be obtained for MnCo-BTC at a rate of 100 mA g^-1 after 150 cycles. Even at a high rate of 500 mA g^-1, its capacity can still reach 445.3 mA h g^-1 after 100 cycles.

Original language	English
Pages (from-to)	61319-61324
Number of pages	6
Journal	RSC Advances
Volume	6
Issue number	66
DOIs	https://doi.org/10.1039/c6ra07727g
State	Published - 2016
Externally published	Yes

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title = "Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal-organic framework with high capacity",

abstract = "Metal-organic frameworks (MOFs), are explosively developed as electrode materials for lithium-ion batteries. Mn-BTC MOF possessed low cycling stability. We therefore attempted to improve the electrochemical properties by doping cobalt into the Mn-BTC. Cobalt doped MnCo-BTC MOF greatly improved the cycling stability compared with Mn-BTC. A high capacity of 901 mA h g-1 could be obtained for MnCo-BTC at a rate of 100 mA g-1 after 150 cycles. Even at a high rate of 500 mA g-1, its capacity can still reach 445.3 mA h g-1 after 100 cycles.",

author = "Tian Li and Chao Li and Xiaoshi Hu and Xiaobing Lou and Huiping Hu and Likun Pan and Qun Chen and Ming Shen and Bingwen Hu",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ra07727g",

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volume = "6",

pages = "61319--61324",

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TY - JOUR

T1 - Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal-organic framework with high capacity

AU - Li, Tian

AU - Li, Chao

AU - Hu, Xiaoshi

AU - Lou, Xiaobing

AU - Hu, Huiping

AU - Pan, Likun

AU - Chen, Qun

AU - Shen, Ming

AU - Hu, Bingwen

PY - 2016

Y1 - 2016

N2 - Metal-organic frameworks (MOFs), are explosively developed as electrode materials for lithium-ion batteries. Mn-BTC MOF possessed low cycling stability. We therefore attempted to improve the electrochemical properties by doping cobalt into the Mn-BTC. Cobalt doped MnCo-BTC MOF greatly improved the cycling stability compared with Mn-BTC. A high capacity of 901 mA h g-1 could be obtained for MnCo-BTC at a rate of 100 mA g-1 after 150 cycles. Even at a high rate of 500 mA g-1, its capacity can still reach 445.3 mA h g-1 after 100 cycles.

AB - Metal-organic frameworks (MOFs), are explosively developed as electrode materials for lithium-ion batteries. Mn-BTC MOF possessed low cycling stability. We therefore attempted to improve the electrochemical properties by doping cobalt into the Mn-BTC. Cobalt doped MnCo-BTC MOF greatly improved the cycling stability compared with Mn-BTC. A high capacity of 901 mA h g-1 could be obtained for MnCo-BTC at a rate of 100 mA g-1 after 150 cycles. Even at a high rate of 500 mA g-1, its capacity can still reach 445.3 mA h g-1 after 100 cycles.

UR - https://www.scopus.com/pages/publications/84976871295

U2 - 10.1039/c6ra07727g

DO - 10.1039/c6ra07727g

M3 - 文章

AN - SCOPUS:84976871295

SN - 2046-2069

VL - 6

SP - 61319

EP - 61324

JO - RSC Advances

JF - RSC Advances

IS - 66

ER -

Reversible lithium storage in manganese and cobalt 1,2,4,5-benzenetetracarboxylate metal-organic framework with high capacity

Abstract

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