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Regioselective synthesis and photooxygenations of furonaphthopyrones starting from 2,7-naphthalenediol

  • Zhi Fu Tao*
  • , Xuhong Qian
  • , Mingcai Fan
  • *Corresponding author for this work
  • East China University of Science and Technology

Research output: Contribution to journalArticlepeer-review

Abstract

Three angular furonaphthopyrones 4, 9, 12 were regioselectively synthesized starting from 2,7-naphthalenediol in three steps, respectively. An easy separation of Pechmann condensation products 1 and 2 of 2, 7-naphthalenediol with ethyl acetoacetate was described. The photooxygenations of 4, 12 were investigated and a hydroperoxide 18 was isolated and fully characterized.

Original languageEnglish
Pages (from-to)13329-13338
Number of pages10
JournalTetrahedron
Volume53
Issue number39
DOIs
StatePublished - 29 Sep 1997
Externally publishedYes

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