Real-Time Monitoring the Dynamics of Coordination-Driven Self-Assembly by Fluorescence-Resonance Energy Transfer

Chang Bo Huang; Lin Xu; Jun Long Zhu; Yu Xuan Wang; Bin Sun; Xiaopeng Li; Hai Bo Yang

doi:10.1021/jacs.7b04659

Real-Time Monitoring the Dynamics of Coordination-Driven Self-Assembly by Fluorescence-Resonance Energy Transfer

Chang Bo Huang
, Lin Xu^*
, Jun Long Zhu
, Yu Xuan Wang
, Bin Sun
, Xiaopeng Li
, Hai Bo Yang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

190 Scopus citations

Abstract

It is quite challenging to investigate the dynamics of coordination-driven self-assembly due to the existence of multiple intermediates and many possible processes. By taking advantage of the high sensitivity and efficiency of fluorescence-resonance energy transfer (FRET), FRET was successfully employed to real-time monitor the dynamic behavior of coordination-driven self-assembly. The Förster energy transfer efficiencies and kinetic aspects of a series of discrete, well-defined metallacycles have been determined. Moreover, the dynamic characteristics of these supramolecular assemblies, such as the dynamic ligand exchange, anion-induced disassembly and reassembly, and stability in different solvents, have been investigated by using FRET.

Original language	English
Pages (from-to)	9459-9462
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	28
DOIs	https://doi.org/10.1021/jacs.7b04659
State	Published - 19 Jul 2017

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title = "Real-Time Monitoring the Dynamics of Coordination-Driven Self-Assembly by Fluorescence-Resonance Energy Transfer",

abstract = "It is quite challenging to investigate the dynamics of coordination-driven self-assembly due to the existence of multiple intermediates and many possible processes. By taking advantage of the high sensitivity and efficiency of fluorescence-resonance energy transfer (FRET), FRET was successfully employed to real-time monitor the dynamic behavior of coordination-driven self-assembly. The F{\"o}rster energy transfer efficiencies and kinetic aspects of a series of discrete, well-defined metallacycles have been determined. Moreover, the dynamic characteristics of these supramolecular assemblies, such as the dynamic ligand exchange, anion-induced disassembly and reassembly, and stability in different solvents, have been investigated by using FRET.",

author = "Huang, \{Chang Bo\} and Lin Xu and Zhu, \{Jun Long\} and Wang, \{Yu Xuan\} and Bin Sun and Xiaopeng Li and Yang, \{Hai Bo\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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doi = "10.1021/jacs.7b04659",

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T1 - Real-Time Monitoring the Dynamics of Coordination-Driven Self-Assembly by Fluorescence-Resonance Energy Transfer

AU - Huang, Chang Bo

AU - Xu, Lin

AU - Zhu, Jun Long

AU - Wang, Yu Xuan

AU - Sun, Bin

AU - Li, Xiaopeng

AU - Yang, Hai Bo

PY - 2017/7/19

Y1 - 2017/7/19

N2 - It is quite challenging to investigate the dynamics of coordination-driven self-assembly due to the existence of multiple intermediates and many possible processes. By taking advantage of the high sensitivity and efficiency of fluorescence-resonance energy transfer (FRET), FRET was successfully employed to real-time monitor the dynamic behavior of coordination-driven self-assembly. The Förster energy transfer efficiencies and kinetic aspects of a series of discrete, well-defined metallacycles have been determined. Moreover, the dynamic characteristics of these supramolecular assemblies, such as the dynamic ligand exchange, anion-induced disassembly and reassembly, and stability in different solvents, have been investigated by using FRET.

AB - It is quite challenging to investigate the dynamics of coordination-driven self-assembly due to the existence of multiple intermediates and many possible processes. By taking advantage of the high sensitivity and efficiency of fluorescence-resonance energy transfer (FRET), FRET was successfully employed to real-time monitor the dynamic behavior of coordination-driven self-assembly. The Förster energy transfer efficiencies and kinetic aspects of a series of discrete, well-defined metallacycles have been determined. Moreover, the dynamic characteristics of these supramolecular assemblies, such as the dynamic ligand exchange, anion-induced disassembly and reassembly, and stability in different solvents, have been investigated by using FRET.

UR - https://www.scopus.com/pages/publications/85024835329

U2 - 10.1021/jacs.7b04659

DO - 10.1021/jacs.7b04659

M3 - 文章

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SN - 0002-7863

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EP - 9462

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 28

ER -

Real-Time Monitoring the Dynamics of Coordination-Driven Self-Assembly by Fluorescence-Resonance Energy Transfer

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