Raman spectra study on the GeS2-Ga2S3-KCl system glasses

Hai Zheng Tao; Xiu Jian Zhao; Cheng Bin Jing; Wei Tong

Raman spectra study on the GeS₂-Ga₂S₃-KCl system glasses

Hai Zheng Tao
, Xiu Jian Zhao^*
, Cheng Bin Jing
, Wei Tong

^*Corresponding author for this work

Wuhan University of Technology

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Raman spectra of GeS₂-Ga₂S₃-KCl pseudo-ternary system glasses at room temperature in the air were probed systematically in the region of 150-500 cm^-1. Based on the results of Raman spectra and preparing procedure in pseudo-binary systems GeS₂-KCl and Ga₂S₃-KCl, the sole interaction of Ga₂S₃ and KCl was identified and new units GaS_3/2Cl were produced in GeS₂-Ga₂S₃-KCl glasses. That K⁺ ions in the form of Cl as the nearest coordination were homogeneously dispersed in the polymeric network was confirmed by the Raman spectra evolution of samples on the serials I and III. Raman spectral evolution of three composition serials can be successfully interpreted using a localized model considering the effect of K⁺ ions on the structural units GaS_3/2Cl and Ga₂S₄Cl₂.

Original language	English
Pages (from-to)	44-47
Number of pages	4
Journal	Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
Volume	25
Issue number	1
State	Published - Jan 2005
Externally published	Yes

Keywords

GaSCl structural units
GeS-GaS-KCl glasses
Raman spectra

Cite this

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title = "Raman spectra study on the GeS2-Ga2S3-KCl system glasses",

abstract = "Raman spectra of GeS2-Ga2S3-KCl pseudo-ternary system glasses at room temperature in the air were probed systematically in the region of 150-500 cm-1. Based on the results of Raman spectra and preparing procedure in pseudo-binary systems GeS2-KCl and Ga2S3-KCl, the sole interaction of Ga2S3 and KCl was identified and new units GaS3/2Cl were produced in GeS2-Ga2S3-KCl glasses. That K+ ions in the form of Cl as the nearest coordination were homogeneously dispersed in the polymeric network was confirmed by the Raman spectra evolution of samples on the serials I and III. Raman spectral evolution of three composition serials can be successfully interpreted using a localized model considering the effect of K+ ions on the structural units GaS3/2Cl and Ga2S4Cl2.",

keywords = "GaSCl structural units, GeS-GaS-KCl glasses, Raman spectra",

author = "Tao, \{Hai Zheng\} and Zhao, \{Xiu Jian\} and Jing, \{Cheng Bin\} and Wei Tong",

year = "2005",

month = jan,

language = "英语",

volume = "25",

pages = "44--47",

journal = "Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis",

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TY - JOUR

T1 - Raman spectra study on the GeS2-Ga2S3-KCl system glasses

AU - Tao, Hai Zheng

AU - Zhao, Xiu Jian

AU - Jing, Cheng Bin

AU - Tong, Wei

PY - 2005/1

Y1 - 2005/1

N2 - Raman spectra of GeS2-Ga2S3-KCl pseudo-ternary system glasses at room temperature in the air were probed systematically in the region of 150-500 cm-1. Based on the results of Raman spectra and preparing procedure in pseudo-binary systems GeS2-KCl and Ga2S3-KCl, the sole interaction of Ga2S3 and KCl was identified and new units GaS3/2Cl were produced in GeS2-Ga2S3-KCl glasses. That K+ ions in the form of Cl as the nearest coordination were homogeneously dispersed in the polymeric network was confirmed by the Raman spectra evolution of samples on the serials I and III. Raman spectral evolution of three composition serials can be successfully interpreted using a localized model considering the effect of K+ ions on the structural units GaS3/2Cl and Ga2S4Cl2.

AB - Raman spectra of GeS2-Ga2S3-KCl pseudo-ternary system glasses at room temperature in the air were probed systematically in the region of 150-500 cm-1. Based on the results of Raman spectra and preparing procedure in pseudo-binary systems GeS2-KCl and Ga2S3-KCl, the sole interaction of Ga2S3 and KCl was identified and new units GaS3/2Cl were produced in GeS2-Ga2S3-KCl glasses. That K+ ions in the form of Cl as the nearest coordination were homogeneously dispersed in the polymeric network was confirmed by the Raman spectra evolution of samples on the serials I and III. Raman spectral evolution of three composition serials can be successfully interpreted using a localized model considering the effect of K+ ions on the structural units GaS3/2Cl and Ga2S4Cl2.

KW - GaSCl structural units

KW - GeS-GaS-KCl glasses

KW - Raman spectra

UR - https://www.scopus.com/pages/publications/14344253381

M3 - 文章

C2 - 15852815

AN - SCOPUS:14344253381

SN - 1000-0593

VL - 25

SP - 44

EP - 47

JO - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

JF - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis

IS - 1

ER -

Raman spectra study on the GeS₂-Ga₂S₃-KCl system glasses

Abstract

Keywords

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