Raman scattering studies of the GeS 2-Ga 2S 3-CsCl glassy system

Tao Haizheng; Zhao Xiujian; Jing Chengbin; Yang Hui; Mao Shun

doi:10.1016/j.ssc.2004.11.010

Raman scattering studies of the GeS ₂-Ga ₂S ₃-CsCl glassy system

Tao Haizheng
, Zhao Xiujian
, Jing Chengbin
, Yang Hui
, Mao Shun

School of Physics and Electronic Science

Ministry of Education of the People's Republic of China

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

Room temperature Raman spectra of samples on four serials within GeS ₂-Ga ₂S ₃-CsCl glassy system have been investigated systematically. Based on the analysis of the local coordination surroundings of Cs ⁺ ions, the similarities and changes of Raman spectra for glass Ga ₂S ₃-2CsCl and bridged molecular GaCl ₃ were explained successfully. With a profound consideration of the effect of Cs ⁺ ions on mixed anion units (GaS _4-xCl _x) and bridged units (Ga ₂S _6-xCl _x) and the corresponding micro-structural model, the Raman spectral evolution of the samples within GeS ₂-Ga ₂S ₃-CsCl glassy system was reasonably elucidated.

Original language	English
Pages (from-to)	327-332
Number of pages	6
Journal	Solid State Communications
Volume	133
Issue number	5
DOIs	https://doi.org/10.1016/j.ssc.2004.11.010
State	Published - Feb 2005

Keywords

A. CsCl
D. Micro-structural units
D. Raman

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10.1016/j.ssc.2004.11.010

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title = "Raman scattering studies of the GeS 2-Ga 2S 3-CsCl glassy system",

abstract = "Room temperature Raman spectra of samples on four serials within GeS 2-Ga 2S 3-CsCl glassy system have been investigated systematically. Based on the analysis of the local coordination surroundings of Cs + ions, the similarities and changes of Raman spectra for glass Ga 2S 3-2CsCl and bridged molecular GaCl 3 were explained successfully. With a profound consideration of the effect of Cs + ions on mixed anion units (GaS 4-xCl x) and bridged units (Ga 2S 6-xCl x) and the corresponding micro-structural model, the Raman spectral evolution of the samples within GeS 2-Ga 2S 3-CsCl glassy system was reasonably elucidated.",

keywords = "A. CsCl, D. Micro-structural units, D. Raman",

author = "Tao Haizheng and Zhao Xiujian and Jing Chengbin and Yang Hui and Mao Shun",

year = "2005",

month = feb,

doi = "10.1016/j.ssc.2004.11.010",

language = "英语",

volume = "133",

pages = "327--332",

journal = "Solid State Communications",

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TY - JOUR

T1 - Raman scattering studies of the GeS 2-Ga 2S 3-CsCl glassy system

AU - Haizheng, Tao

AU - Xiujian, Zhao

AU - Chengbin, Jing

AU - Hui, Yang

AU - Shun, Mao

PY - 2005/2

Y1 - 2005/2

N2 - Room temperature Raman spectra of samples on four serials within GeS 2-Ga 2S 3-CsCl glassy system have been investigated systematically. Based on the analysis of the local coordination surroundings of Cs + ions, the similarities and changes of Raman spectra for glass Ga 2S 3-2CsCl and bridged molecular GaCl 3 were explained successfully. With a profound consideration of the effect of Cs + ions on mixed anion units (GaS 4-xCl x) and bridged units (Ga 2S 6-xCl x) and the corresponding micro-structural model, the Raman spectral evolution of the samples within GeS 2-Ga 2S 3-CsCl glassy system was reasonably elucidated.

AB - Room temperature Raman spectra of samples on four serials within GeS 2-Ga 2S 3-CsCl glassy system have been investigated systematically. Based on the analysis of the local coordination surroundings of Cs + ions, the similarities and changes of Raman spectra for glass Ga 2S 3-2CsCl and bridged molecular GaCl 3 were explained successfully. With a profound consideration of the effect of Cs + ions on mixed anion units (GaS 4-xCl x) and bridged units (Ga 2S 6-xCl x) and the corresponding micro-structural model, the Raman spectral evolution of the samples within GeS 2-Ga 2S 3-CsCl glassy system was reasonably elucidated.

KW - A. CsCl

KW - D. Micro-structural units

KW - D. Raman

UR - https://www.scopus.com/pages/publications/11244255119

U2 - 10.1016/j.ssc.2004.11.010

DO - 10.1016/j.ssc.2004.11.010

M3 - 文章

AN - SCOPUS:11244255119

SN - 0038-1098

VL - 133

SP - 327

EP - 332

JO - Solid State Communications

JF - Solid State Communications

IS - 5

ER -

Raman scattering studies of the GeS ₂-Ga ₂S ₃-CsCl glassy system

Abstract

Keywords

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