Radical aromatic substitutions on (η6-chloroarene)tricarbonylchromium complexes

Hechun Lin; Li Yang; Chaozhong Li

doi:10.1021/om020466l

Radical aromatic substitutions on (η⁶-chloroarene)tricarbonylchromium complexes

Hechun Lin
, Li Yang
, Chaozhong Li^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The radical aromatic substitutions on chloroarene-Cr(CO)₃ complexes were performed by reaction with SmI₂ and ketones or aldehydes. The methyl substitution on the phenyl ring shows the meta-directing effect on the radical addition. The results indicate that the mechanism is preferably meta-tele-substitution.

Original language	English
Pages (from-to)	3848-3849
Number of pages	2
Journal	Organometallics
Volume	21
Issue number	19
DOIs	https://doi.org/10.1021/om020466l
State	Published - 16 Sep 2002
Externally published	Yes

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title = "Radical aromatic substitutions on (η6-chloroarene)tricarbonylchromium complexes",

abstract = "The radical aromatic substitutions on chloroarene-Cr(CO)3 complexes were performed by reaction with SmI2 and ketones or aldehydes. The methyl substitution on the phenyl ring shows the meta-directing effect on the radical addition. The results indicate that the mechanism is preferably meta-tele-substitution.",

author = "Hechun Lin and Li Yang and Chaozhong Li",

year = "2002",

month = sep,

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doi = "10.1021/om020466l",

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T1 - Radical aromatic substitutions on (η6-chloroarene)tricarbonylchromium complexes

AU - Lin, Hechun

AU - Yang, Li

AU - Li, Chaozhong

PY - 2002/9/16

Y1 - 2002/9/16

N2 - The radical aromatic substitutions on chloroarene-Cr(CO)3 complexes were performed by reaction with SmI2 and ketones or aldehydes. The methyl substitution on the phenyl ring shows the meta-directing effect on the radical addition. The results indicate that the mechanism is preferably meta-tele-substitution.

AB - The radical aromatic substitutions on chloroarene-Cr(CO)3 complexes were performed by reaction with SmI2 and ketones or aldehydes. The methyl substitution on the phenyl ring shows the meta-directing effect on the radical addition. The results indicate that the mechanism is preferably meta-tele-substitution.

UR - https://www.scopus.com/pages/publications/0038344218

U2 - 10.1021/om020466l

DO - 10.1021/om020466l

M3 - 文章

AN - SCOPUS:0038344218

SN - 0276-7333

VL - 21

SP - 3848

EP - 3849

JO - Organometallics

JF - Organometallics

IS - 19

ER -

Radical aromatic substitutions on (η⁶-chloroarene)tricarbonylchromium complexes

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