TY - JOUR
T1 - Pyridinium conjugated ferrocenes with thien and bithien bridges
T2 - Synthesis and electrochemical properties
AU - Yonghua, Gong
AU - Wenwei, Qiu
AU - Fan, Yang
AU - Pierre, Audebert
AU - Gilles, Clavier
AU - Fabien, Miomandre
AU - Jie, Tang
PY - 2009/8
Y1 - 2009/8
N2 - Three di- and tri-branched pyridinium salts with ferrocene ends and thienyl or bithienyl bridges, (E,E)-N-methyl-2,4,6-tris{2-[5-(2-ferrocenylvinyl)thien-2-yl]vinyl} pyridinium iodide, (E,E)-N-methyl-2,6-bis-{2-[5'-(2-ferrocenylvinyl)-2,2'-bithien-5-yl]vinyl} pyridinium iodide, and (E,E)-N-methyl-2,4,6-tris-{2-[5'-(2-ferrocenylvinyl)-2,2'-bithien-5-yl]vinyl}pyridinium iodide, were designed and successfully synthesized. The electrochemical properties of these compounds were primarily investigated, showing that most of these multiferrocenyl pyridinium salts are potential electrochemical molecular materials with good oxidation-reduction reversibility.
AB - Three di- and tri-branched pyridinium salts with ferrocene ends and thienyl or bithienyl bridges, (E,E)-N-methyl-2,4,6-tris{2-[5-(2-ferrocenylvinyl)thien-2-yl]vinyl} pyridinium iodide, (E,E)-N-methyl-2,6-bis-{2-[5'-(2-ferrocenylvinyl)-2,2'-bithien-5-yl]vinyl} pyridinium iodide, and (E,E)-N-methyl-2,4,6-tris-{2-[5'-(2-ferrocenylvinyl)-2,2'-bithien-5-yl]vinyl}pyridinium iodide, were designed and successfully synthesized. The electrochemical properties of these compounds were primarily investigated, showing that most of these multiferrocenyl pyridinium salts are potential electrochemical molecular materials with good oxidation-reduction reversibility.
KW - Bithien
KW - Electrochemical property
KW - Pyridinium
KW - Synthesis
KW - Thien
UR - https://www.scopus.com/pages/publications/70449124441
U2 - 10.1002/cjoc.200990255
DO - 10.1002/cjoc.200990255
M3 - 文章
AN - SCOPUS:70449124441
SN - 1001-604X
VL - 27
SP - 1515
EP - 1522
JO - Chinese Journal of Chemistry
JF - Chinese Journal of Chemistry
IS - 8
ER -